hexatetracontafluorohexatetracontahydro[5,6]fullerene (C60F46)
- Formula: C60F46
- Molecular weight: 1594.5685
- CAS Registry Number: 143471-96-9
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
3.33 ± 0.10 | LPES | Wang, Chi, et al., 2010 | Reverse Coulombic barrier estimated as 1.0±0.1 eV |
3.20 ± 0.10 | LPES | Ioffe, Avdoshenko, et al., 2005 | |
4.06 ± 0.25 | IMRB | Hettich, Jin, et al., 1994 | EA between NO3-, CF3CO2- |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wang, Chi, et al., 2010
Wang, X.B.; Chi, C.X.; Zhou, M.F.; Kuvychko, I.V.; Seppelt, K.; Popov, A.A.; Strauss, S.H.; Boltalina, O.V.; Wang, L.S.,
Photoelectron Spectroscopy of C60Fn- and C60Fm2- (n=17, 33, 35, 43, 45, 47; m=34, 46) in the Gas Phase and the Generation and Characterization of C-1-C60F47- and D-2-C60F44 in Solution,
J. Phys. Chem. A, 2010, 114, 4, 1756-1765, https://doi.org/10.1021/jp9097364
. [all data]
Ioffe, Avdoshenko, et al., 2005
Ioffe, I.N.; Avdoshenko, S.M.; Boltalina, O.V.; Sidorov, L.N.; Berndt, K.; Weber, J.M.,
Mass spectrometry, photoelectron spectroscopy, and quantum chemical studies of fluorofullerene dianions,
Int. J. Mass Spectrom., 2005, 243, 3, 223-230, https://doi.org/10.1016/j.ijms.2005.03.005
. [all data]
Hettich, Jin, et al., 1994
Hettich, R.; Jin, C.M.; Compton, R.,
Determination of the electron affinities of fluorinated fullerenes (C60F44,46, C70F52,54) by Fourier transform mass spectrometry,
Int. J. Mass Spectrom. Ion Proc., 1994, 138, 263, https://doi.org/10.1016/0168-1176(94)04059-1
. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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