Sulfur anion
- Formula: S-
- Molecular weight: 32.066
- CAS Registry Number: 14337-03-2
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 350.150 ± 0.070 | kcal/mol | D-EA | Blondel, Chaibi, et al., 2005 | gas phase; (32)S: 2.0771040(9) eV: revised analysis of Blondel, Delsart, et al., 2001 |
ΔrH° | 350.2 ± 2.9 | kcal/mol | Endo | Rempala and Ervin, 2000 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 344.61 ± 0.19 | kcal/mol | H-TS | Blondel, Chaibi, et al., 2005 | gas phase; (32)S: 2.0771040(9) eV: revised analysis of Blondel, Delsart, et al., 2001 |
ΔrG° | 344.7 ± 3.0 | kcal/mol | H-TS | Rempala and Ervin, 2000 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 350.150 ± 0.070 | kcal/mol | D-EA | Blondel, Chaibi, et al., 2005 | gas phase; (32)S: 2.0771040(9) eV: revised analysis of Blondel, Delsart, et al., 2001 |
ΔrH° | 350.2 ± 2.9 | kcal/mol | Endo | Rempala and Ervin, 2000 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 344.61 ± 0.19 | kcal/mol | H-TS | Blondel, Chaibi, et al., 2005 | gas phase; (32)S: 2.0771040(9) eV: revised analysis of Blondel, Delsart, et al., 2001 |
ΔrG° | 344.7 ± 3.0 | kcal/mol | H-TS | Rempala and Ervin, 2000 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Blondel, Chaibi, et al., 2005
Blondel, C.; Chaibi, W.; Delsart, C.; Drag, C.; Goldfarb, F.; Kroger, S.,
The electron affinities of O, Si, and S revisited with the photodetachment microscope,
Eur. Phys. J. D, 2005, 33, 3, 335-342, https://doi.org/10.1140/epjd/e2005-00069-9
. [all data]
Blondel, Delsart, et al., 2001
Blondel, C.; Delsart, C.; Goldfarb, F.,
Electron spectrometry at the mu eV level and the electron affinities of Si and F,
J. Phys. B: Atom. Mol. Opt. Phys., 2001, 34, 9, L281-L288, https://doi.org/10.1088/0953-4075/34/9/101
. [all data]
Rempala and Ervin, 2000
Rempala, K.; Ervin, K.M.,
Collisional activation of the Endoergic Hydrogen Atom Transfer Reaction S-(2P) + H2 - SH- + H,
J. Chem. Phys., 2000, 112, 10, 4579, https://doi.org/10.1063/1.481016
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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