Oxygen anion
- Formula: O-
- Molecular weight: 15.9999
- CAS Registry Number: 14337-01-0
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: O- + Ar = (O- • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.2 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • Ar) + Ar = (O- • 2Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 2Ar) + Ar = (O- • 3Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.7 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 3Ar) + Ar = (O- • 4Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.9 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 4Ar) + Ar = (O- • 5Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.0 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 5Ar) + Ar = (O- • 6Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.0 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 6Ar) + Ar = (O- • 7Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.2 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 7Ar) + Ar = (O- • 8Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4. ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 8Ar) + Ar = (O- • 9Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4. ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 9Ar) + Ar = (O- • 10Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3. ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 10Ar) + Ar = (O- • 11Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2. ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 11Ar) + Ar = (O- • 12Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3. ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 12Ar) + Ar = (O- • 13Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.8 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 13Ar) + Ar = (O- • 14Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.8 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 14Ar) + Ar = (O- • 15Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2. ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 15Ar) + Ar = (O- • 16Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 16Ar) + Ar = (O- • 17Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 17Ar) + Ar = (O- • 18Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.8 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 18Ar) + Ar = (O- • 19Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 19Ar) + Ar = (O- • 20Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 20Ar) + Ar = (O- • 21Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 21Ar) + Ar = (O- • 22Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 22Ar) + Ar = (O- • 23Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 23Ar) + Ar = (O- • 24Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.4 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 24Ar) + Ar = (O- • 25Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.8 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (O- • 25Ar) + Ar = (O- • 26Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.8 ± 8.4 | kJ/mol | N/A | Arnold, Hendricks, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: O- + CO2 = (O- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 200. ± 50. | kJ/mol | AVG | N/A | Average of 8 out of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 201. ± 21. | kJ/mol | IMRE | Adams and Bohme, 1970 | gas phase; O3- + CO2 <=> CO3- + O2; B |
By formula: (O- • CO2) + CO2 = (O- • 2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. | kJ/mol | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 91.2 | J/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
O- + = D2O2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 101. ± 7.5 | kJ/mol | PDis | Deyerl, Clements, et al., 2001 | gas phase; B |
By formula: O- + H2O = (O- • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 111. ± 7.5 | kJ/mol | PDis | Deyerl, Clements, et al., 2001 | gas phase; B |
ΔrH° | 2.2 | kJ/mol | N/A | Arnold, Xu, et al., 1995 | gas phase; Vertical Detachment Energy: 1.45 eV. Affinity is difference between EA of O-. and HOH..O-.; B |
ΔrH° | 126. | kJ/mol | PDiss | Roehl, Snodgrass, et al., 1991 | gas phase; ΔrH<; M |
ΔrH° | 130. | kJ/mol | FA | Fehsenfeld and Ferguson, 1974 | gas phase; bracketing, ΔrH<; M |
By formula: (O- • H2O) + CO2 = (O- • CO2 • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 152. | kJ/mol | PDiss | Roehl, Snodgrass, et al., 1991 | gas phase; ΔrH>; M |
By formula: (O- • N2O) + N2O = (O- • 2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.6 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -1. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
By formula: (O- • 2N2O) + N2O = (O- • 3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.6 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 88. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -4. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
By formula: (O- • 3N2O) + N2O = (O- • 4N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.8 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -8.4 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
By formula: (O- • 4N2O) + N2O = (O- • 5N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.8 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -9.6 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
By formula: (O- • 5N2O) + N2O = (O- • 6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.3 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -11. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
By formula: (O- • 6N2O) + N2O = (O- • 7N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.3 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 120. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -14. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
By formula: O- + O2S = (O- • O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 250. | kJ/mol | FA | Fehsenfeld and Ferguson, 1974 | gas phase; switching reaction(O-)CO2, ΔrH>; Hiller and Vestal, 1980, Keesee and Castleman, 1986; M |
By formula: (O- • O2S) + O2S = (O- • 2O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 55.6 | kJ/mol | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.1 | J/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
By formula: O- + O2 = (O- • O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 130. | kJ/mol | PDiss | Hiller and Vestal, 1981 | gas phase; From thermochemical cycle, ΔrH<; M |
ΔrH° | 163. | kJ/mol | PES | Novich, Engelking, et al., 1979 | gas phase; From thermochemical cycle, from EA(O3), D(O-O2) AND EA(O); M |
ΔrH° | 160. | kJ/mol | PDiss | Cosby, Moseley, et al., 1978 | gas phase; M |
ΔrH° | 180. | kJ/mol | CID | Lifschitz, Wu, et al., 1978 | gas phase; M |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Arnold, Hendricks, et al., 1995
Arnold, S.T.; Hendricks, J.H.; Bowen, K.H.,
Photoelectron spectroscopy of the solvated anion clusters O-(Ar)(n=1-26,34): Energetics and structure,
J. Chem. Phys., 1995, 102, 1, 39, https://doi.org/10.1063/1.469415
. [all data]
Adams and Bohme, 1970
Adams, N.G.; Bohme, D.,
Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-,
J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449
. [all data]
Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr.,
Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions,
J. Chem. Phys., 1980, 73, 2195. [all data]
Deyerl, Clements, et al., 2001
Deyerl, H.J.; Clements, T.G.; Luong, A.K.; Continetti, R.E.,
Transition state dynamics of the OH+OH - O+H2O reaction studied by dissociative photodetachment of H2O2-,
J. Chem. Phys., 2001, 115, 15, 6931-6940, https://doi.org/10.1063/1.1404148
. [all data]
Arnold, Xu, et al., 1995
Arnold, D.W.; Xu, C.S.; Neumark, D.M.,
Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied by photoelectron spectroscopy of O-(H2O) and H3O2,
J. Chem. Phys., 1995, 102, 15, 6088, https://doi.org/10.1063/1.469343
. [all data]
Roehl, Snodgrass, et al., 1991
Roehl, C.M.; Snodgrass, J.T.; Deakyne, C.A.; Bowers, M.T.,
Photodissociation of CO3-.H2O: Observation of the O-.H2O + CO2 Product Channel,
J. Chem. Phys., 1991, 94, 10, 6546, https://doi.org/10.1063/1.460281
. [all data]
Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E.,
Laboratory studies of negative ion reactions with atmospheric trace constituents,
J. Chem. Phys., 1974, 61, 3181. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S.,
Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-),
J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006
. [all data]
Hiller and Vestal, 1980
Hiller, J.F.; Vestal, M.L.,
Tandem quadrupole study of laser photodissociation of CO3-,
J. Chem. Phys., 1980, 72, 4713. [all data]
Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr.,
Thermochemical data on Ggs-phase ion-molecule association and clustering reactions,
J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]
Hiller and Vestal, 1981
Hiller, J.F.; Vestal, M.L.,
Laser Photodissociation of O3- by Triple Quadrupole Mass Spectrometry,
J. Chem. Phys., 1981, 74, 11, 6096, https://doi.org/10.1063/1.441053
. [all data]
Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C.,
Laser photoelectron, photodetachment, and photodestruction spectra of O3-,
J. Chem. Phys., 1979, 70, 2652. [all data]
Cosby, Moseley, et al., 1978
Cosby, P.C.; Moseley, J.T.; Peterson, J.R.; Ling, J.H.,
Photodissociation spectroscopy of O3,
J. Chem. Phys., 1978, 69, 2771. [all data]
Lifschitz, Wu, et al., 1978
Lifschitz, C.; Wu, R.L.C.; Tiernan, T.O.; Terwillinger, D.T.,
Negative Ion - Molecule Reactions of Ozone and Their Implications on the Thermochemistry of O3-,
J. Chem. Phys., 1978, 68, 1, 247, https://doi.org/10.1063/1.435489
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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