Oxygen anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas25.88kcal/molR-EABlondel, Chaibi, et al., 2005(16)O: 1.4611135(12) eV: revised analysis of Blondel, Delsart, et al., 2001; B
Quantity Value Units Method Reference Comment
gas,1 bar37.713cal/mol*KReviewChase, 1998Data last reviewed in September, 1982

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O- + Carbon dioxide = (O- • Carbon dioxide)

By formula: O- + CO2 = (O- • CO2)

Quantity Value Units Method Reference Comment
Δr48. ± 10.kcal/molAVGN/AAverage of 8 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Δr48.0 ± 5.0kcal/molIMREAdams and Bohme, 1970gas phase; O3- + CO2 <=> CO3- + O2; B

O- + Water = (O- • Water)

By formula: O- + H2O = (O- • H2O)

Quantity Value Units Method Reference Comment
Δr26.5 ± 1.8kcal/molPDisDeyerl, Clements, et al., 2001gas phase; B
Δr0.52kcal/molN/AArnold, Xu, et al., 1995gas phase; Vertical Detachment Energy: 1.45 eV. Affinity is difference between EA of O-. and HOH..O-.; B
Δr30.0kcal/molPDissRoehl, Snodgrass, et al., 1991gas phase; ΔrH<; M
Δr30.kcal/molFAFehsenfeld and Ferguson, 1974gas phase; bracketing, ΔrH<; M

O- + Hydrogen cation = Hydroxyl radical

By formula: O- + H+ = HO

Quantity Value Units Method Reference Comment
Δr382.600 ± 0.010kcal/molD-EANeumark, Lykke, et al., 1985gas phase; Given: 1.461122(3) eV; revised to 1.4611107(17) eV, 95BLO, based on missing term+86CODATA; B
Quantity Value Units Method Reference Comment
Δr376.73 ± 0.15kcal/molH-TSNeumark, Lykke, et al., 1985gas phase; Given: 1.461122(3) eV; revised to 1.4611107(17) eV, 95BLO, based on missing term+86CODATA; B

O- + Oxygen = (O- • Oxygen)

By formula: O- + O2 = (O- • O2)

Quantity Value Units Method Reference Comment
Δr32.kcal/molPDissHiller and Vestal, 1981gas phase; From thermochemical cycle, ΔrH<; M
Δr39.0kcal/molPESNovich, Engelking, et al., 1979gas phase; From thermochemical cycle, from EA(O3), D(O-O2) AND EA(O); M
Δr38.kcal/molPDissCosby, Moseley, et al., 1978gas phase; M
Δr42.kcal/molCIDLifschitz, Wu, et al., 1978gas phase; M

(O- • 2Nitrous oxide) + Nitrous oxide = (O- • 3Nitrous oxide)

By formula: (O- • 2N2O) + N2O = (O- • 3N2O)

Quantity Value Units Method Reference Comment
Δr5.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Δr21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr-0.9 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- • 3Nitrous oxide) + Nitrous oxide = (O- • 4Nitrous oxide)

By formula: (O- • 3N2O) + N2O = (O- • 4N2O)

Quantity Value Units Method Reference Comment
Δr5.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Δr24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.0 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- • 4Nitrous oxide) + Nitrous oxide = (O- • 5Nitrous oxide)

By formula: (O- • 4N2O) + N2O = (O- • 5N2O)

Quantity Value Units Method Reference Comment
Δr5.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Δr25.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- • 5Nitrous oxide) + Nitrous oxide = (O- • 6Nitrous oxide)

By formula: (O- • 5N2O) + N2O = (O- • 6N2O)

Quantity Value Units Method Reference Comment
Δr5.10 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Δr26.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.7 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- • 6Nitrous oxide) + Nitrous oxide = (O- • 7Nitrous oxide)

By formula: (O- • 6N2O) + N2O = (O- • 7N2O)

Quantity Value Units Method Reference Comment
Δr5.10 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr-3.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- • Nitrous oxide) + Nitrous oxide = (O- • 2Nitrous oxide)

By formula: (O- • N2O) + N2O = (O- • 2N2O)

Quantity Value Units Method Reference Comment
Δr5.40 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr-0.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(O- • 10Argon) + Argon = (O- • 11Argon)

By formula: (O- • 10Ar) + Ar = (O- • 11Ar)

Quantity Value Units Method Reference Comment
Δr0.4 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 11Argon) + Argon = (O- • 12Argon)

By formula: (O- • 11Ar) + Ar = (O- • 12Ar)

Quantity Value Units Method Reference Comment
Δr0.8 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 12Argon) + Argon = (O- • 13Argon)

By formula: (O- • 12Ar) + Ar = (O- • 13Ar)

Quantity Value Units Method Reference Comment
Δr0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 13Argon) + Argon = (O- • 14Argon)

By formula: (O- • 13Ar) + Ar = (O- • 14Ar)

Quantity Value Units Method Reference Comment
Δr0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 14Argon) + Argon = (O- • 15Argon)

By formula: (O- • 14Ar) + Ar = (O- • 15Ar)

Quantity Value Units Method Reference Comment
Δr0.4 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 15Argon) + Argon = (O- • 16Argon)

By formula: (O- • 15Ar) + Ar = (O- • 16Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 16Argon) + Argon = (O- • 17Argon)

By formula: (O- • 16Ar) + Ar = (O- • 17Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 17Argon) + Argon = (O- • 18Argon)

By formula: (O- • 17Ar) + Ar = (O- • 18Ar)

Quantity Value Units Method Reference Comment
Δr0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 18Argon) + Argon = (O- • 19Argon)

By formula: (O- • 18Ar) + Ar = (O- • 19Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 19Argon) + Argon = (O- • 20Argon)

By formula: (O- • 19Ar) + Ar = (O- • 20Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 20Argon) + Argon = (O- • 21Argon)

By formula: (O- • 20Ar) + Ar = (O- • 21Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 21Argon) + Argon = (O- • 22Argon)

By formula: (O- • 21Ar) + Ar = (O- • 22Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 22Argon) + Argon = (O- • 23Argon)

By formula: (O- • 22Ar) + Ar = (O- • 23Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 23Argon) + Argon = (O- • 24Argon)

By formula: (O- • 23Ar) + Ar = (O- • 24Ar)

Quantity Value Units Method Reference Comment
Δr0.1 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 24Argon) + Argon = (O- • 25Argon)

By formula: (O- • 24Ar) + Ar = (O- • 25Ar)

Quantity Value Units Method Reference Comment
Δr0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 25Argon) + Argon = (O- • 26Argon)

By formula: (O- • 25Ar) + Ar = (O- • 26Ar)

Quantity Value Units Method Reference Comment
Δr0.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 9Argon) + Argon = (O- • 10Argon)

By formula: (O- • 9Ar) + Ar = (O- • 10Ar)

Quantity Value Units Method Reference Comment
Δr0.7 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 2Argon) + Argon = (O- • 3Argon)

By formula: (O- • 2Ar) + Ar = (O- • 3Ar)

Quantity Value Units Method Reference Comment
Δr1.6 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 3Argon) + Argon = (O- • 4Argon)

By formula: (O- • 3Ar) + Ar = (O- • 4Ar)

Quantity Value Units Method Reference Comment
Δr1.4 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 4Argon) + Argon = (O- • 5Argon)

By formula: (O- • 4Ar) + Ar = (O- • 5Ar)

Quantity Value Units Method Reference Comment
Δr1.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 5Argon) + Argon = (O- • 6Argon)

By formula: (O- • 5Ar) + Ar = (O- • 6Ar)

Quantity Value Units Method Reference Comment
Δr1.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 6Argon) + Argon = (O- • 7Argon)

By formula: (O- • 6Ar) + Ar = (O- • 7Ar)

Quantity Value Units Method Reference Comment
Δr1.0 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 7Argon) + Argon = (O- • 8Argon)

By formula: (O- • 7Ar) + Ar = (O- • 8Ar)

Quantity Value Units Method Reference Comment
Δr0.9 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • 8Argon) + Argon = (O- • 9Argon)

By formula: (O- • 8Ar) + Ar = (O- • 9Ar)

Quantity Value Units Method Reference Comment
Δr0.9 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • Argon) + Argon = (O- • 2Argon)

By formula: (O- • Ar) + Ar = (O- • 2Ar)

Quantity Value Units Method Reference Comment
Δr2.0 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

O- + Argon = (O- • Argon)

By formula: O- + Ar = (O- • Ar)

Quantity Value Units Method Reference Comment
Δr2.2 ± 2.0kcal/molN/AArnold, Hendricks, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(O- • Sulfur dioxide) + Sulfur dioxide = (O- • 2Sulfur dioxide)

By formula: (O- • O2S) + O2S = (O- • 2O2S)

Quantity Value Units Method Reference Comment
Δr13.3kcal/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr18.9cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M

(O- • Carbon dioxide) + Carbon dioxide = (O- • 2Carbon dioxide)

By formula: (O- • CO2) + CO2 = (O- • 2CO2)

Quantity Value Units Method Reference Comment
Δr7.1kcal/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr21.8cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M

O- + Sulfur dioxide = (O- • Sulfur dioxide)

By formula: O- + O2S = (O- • O2S)

Quantity Value Units Method Reference Comment
Δr60.kcal/molFAFehsenfeld and Ferguson, 1974gas phase; switching reaction(O-)CO2, ΔrH>; Hiller and Vestal, 1980, Keesee and Castleman, 1986; M

(O- • Water) + Carbon dioxide = (O- • Carbon dioxide • Water)

By formula: (O- • H2O) + CO2 = (O- • CO2 • H2O)

Quantity Value Units Method Reference Comment
Δr36.4kcal/molPDissRoehl, Snodgrass, et al., 1991gas phase; ΔrH>; M

O- + Deuterium oxide = D2O2-

By formula: O- + D2O = D2O2-

Quantity Value Units Method Reference Comment
Δr24.2 ± 1.8kcal/molPDisDeyerl, Clements, et al., 2001gas phase; B

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blondel, Chaibi, et al., 2005
Blondel, C.; Chaibi, W.; Delsart, C.; Drag, C.; Goldfarb, F.; Kroger, S., The electron affinities of O, Si, and S revisited with the photodetachment microscope, Eur. Phys. J. D, 2005, 33, 3, 335-342, https://doi.org/10.1140/epjd/e2005-00069-9 . [all data]

Blondel, Delsart, et al., 2001
Blondel, C.; Delsart, C.; Goldfarb, F., Electron spectrometry at the mu eV level and the electron affinities of Si and F, J. Phys. B: Atom. Mol. Opt. Phys., 2001, 34, 9, L281-L288, https://doi.org/10.1088/0953-4075/34/9/101 . [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Adams and Bohme, 1970
Adams, N.G.; Bohme, D., Flowing Afterglow Studies of Formation and Reactions of Cluster Ions of O2+, O2-, and O-, J. Chem. Phys., 1970, 52, 6, 3133, https://doi.org/10.1063/1.1673449 . [all data]

Deyerl, Clements, et al., 2001
Deyerl, H.J.; Clements, T.G.; Luong, A.K.; Continetti, R.E., Transition state dynamics of the OH+OH - O+H2O reaction studied by dissociative photodetachment of H2O2-, J. Chem. Phys., 2001, 115, 15, 6931-6940, https://doi.org/10.1063/1.1404148 . [all data]

Arnold, Xu, et al., 1995
Arnold, D.W.; Xu, C.S.; Neumark, D.M., Spectroscopy of the transition state: Elementary reactions of the hydroxyl radical studied by photoelectron spectroscopy of O-(H2O) and H3O2, J. Chem. Phys., 1995, 102, 15, 6088, https://doi.org/10.1063/1.469343 . [all data]

Roehl, Snodgrass, et al., 1991
Roehl, C.M.; Snodgrass, J.T.; Deakyne, C.A.; Bowers, M.T., Photodissociation of CO3-.H2O: Observation of the O-.H2O + CO2 Product Channel, J. Chem. Phys., 1991, 94, 10, 6546, https://doi.org/10.1063/1.460281 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Neumark, Lykke, et al., 1985
Neumark, D.M.; Lykke, K.R.; Andersen, T.; Lineberger, W.C., Laser photodetachment measurement of the electron affinity of atomic oxygen, Phys. Rev. A:, 1985, 32, 1890. [all data]

Hiller and Vestal, 1981
Hiller, J.F.; Vestal, M.L., Laser Photodissociation of O3- by Triple Quadrupole Mass Spectrometry, J. Chem. Phys., 1981, 74, 11, 6096, https://doi.org/10.1063/1.441053 . [all data]

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Cosby, Moseley, et al., 1978
Cosby, P.C.; Moseley, J.T.; Peterson, J.R.; Ling, J.H., Photodissociation spectroscopy of O3, J. Chem. Phys., 1978, 69, 2771. [all data]

Lifschitz, Wu, et al., 1978
Lifschitz, C.; Wu, R.L.C.; Tiernan, T.O.; Terwillinger, D.T., Negative Ion - Molecule Reactions of Ozone and Their Implications on the Thermochemistry of O3-, J. Chem. Phys., 1978, 68, 1, 247, https://doi.org/10.1063/1.435489 . [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-), J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006 . [all data]

Arnold, Hendricks, et al., 1995
Arnold, S.T.; Hendricks, J.H.; Bowen, K.H., Photoelectron spectroscopy of the solvated anion clusters O-(Ar)(n=1-26,34): Energetics and structure, J. Chem. Phys., 1995, 102, 1, 39, https://doi.org/10.1063/1.469415 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Hiller and Vestal, 1980
Hiller, J.F.; Vestal, M.L., Tandem quadrupole study of laser photodissociation of CO3-, J. Chem. Phys., 1980, 72, 4713. [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]


Notes

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