Scandium ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Scandium ion (1+) + Ethylene = (Scandium ion (1+) • Ethylene)

By formula: Sc+ + C2H4 = (Sc+ • C2H4)

Quantity Value Units Method Reference Comment
Δr220. ± 10.kJ/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
131. CIDArmentrout and Kickel, 1994gas phase; ΔrH >=, guided ion beam CID; M

Scandium ion (1+) + Acetylene = (Scandium ion (1+) • Acetylene)

By formula: Sc+ + C2H2 = (Sc+ • C2H2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
240. (+20.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Scandium ion (1+) + Water = (Scandium ion (1+) • Water)

By formula: Sc+ + H2O = (Sc+ • H2O)

Quantity Value Units Method Reference Comment
Δr130. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M

Scandium ion (1+) + Methylene = (Scandium ion (1+) • Methylene)

By formula: Sc+ + CH2 = (Sc+ • CH2)

Quantity Value Units Method Reference Comment
Δr411. ± 22.kJ/molCIDTSunderlin and Armentrout, 1989RCD

Scandium ion (1+) + Pyridine = (Scandium ion (1+) • Pyridine)

By formula: Sc+ + C5H5N = (Sc+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr231. ± 10.kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) • Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ • CS)

Quantity Value Units Method Reference Comment
Δr133. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Scandium ion (1+) + 1,3-Diazine = (Scandium ion (1+) • 1,3-Diazine)

By formula: Sc+ + C4H4N2 = (Sc+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr214. ± 9.2kJ/molCIDTAmunugama and Rodgers, 2001RCD

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Scandium ion (1+) + Methylene = (Scandium ion (1+) • Methylene)

By formula: Sc+ + CH2 = (Sc+ • CH2)

Quantity Value Units Method Reference Comment
Δr411. ± 22.kJ/molCIDTSunderlin and Armentrout, 1989RCD

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) • Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ • CS)

Quantity Value Units Method Reference Comment
Δr133. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Scandium ion (1+) + Acetylene = (Scandium ion (1+) • Acetylene)

By formula: Sc+ + C2H2 = (Sc+ • C2H2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
240. (+20.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Scandium ion (1+) + Ethylene = (Scandium ion (1+) • Ethylene)

By formula: Sc+ + C2H4 = (Sc+ • C2H4)

Quantity Value Units Method Reference Comment
Δr220. ± 10.kJ/molPDissRanashinge and Freiser, 1992gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
131. CIDArmentrout and Kickel, 1994gas phase; ΔrH >=, guided ion beam CID; M

Scandium ion (1+) + 1,3-Diazine = (Scandium ion (1+) • 1,3-Diazine)

By formula: Sc+ + C4H4N2 = (Sc+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr214. ± 9.2kJ/molCIDTAmunugama and Rodgers, 2001RCD

Scandium ion (1+) + Pyridine = (Scandium ion (1+) • Pyridine)

By formula: Sc+ + C5H5N = (Sc+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr231. ± 10.kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Scandium ion (1+) + Water = (Scandium ion (1+) • Water)

By formula: Sc+ + H2O = (Sc+ • H2O)

Quantity Value Units Method Reference Comment
Δr130. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ranashinge and Freiser, 1992
Ranashinge, Y.A.; Freiser, B.S., Gas-Phase Photodissociation of MC2H2+ (M = Sc, Y, La). Determination of D0(M+ - C2H2), Chem. Phys. Let., 1992, 200, 1-2, 135, https://doi.org/10.1016/0009-2614(92)87058-W . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Sunderlin and Armentrout, 1989
Sunderlin, L.S.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with Methane and Ethane, J. Am. Chem. Soc., 1989, 111, 11, 3845, https://doi.org/10.1021/ja00193a015 . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]


Notes

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