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bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub115.9 ± 2.4kJ/molN/ARibeiro da Silva, 1995 
Deltasub117.0 ± 1.6kJ/molN/ARibeiro da Silva, 1995 
Deltasub112. ± 3.0kJ/molCRibeiro da Silva and Ferrão, 1988 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
112.373. - 403.TGAFahlman and Barron, 2000 
113.3 ± 2.4350.TERibeiro da Silva, 1995Based on data from 342. - 359. K.
114.4 ± 1.6350.MERibeiro da Silva, 1995Based on data from 342. - 359. K.
110.0 ± 0.8383. - 463.GSMatsubara and Kuwamoto, 1985 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, 1995
Ribeiro da Silva, M., Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) «beta»-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014 . [all data]

Ribeiro da Silva and Ferrão, 1988
Ribeiro da Silva, Manuel A.V.; Ferrão, Maria Luisa C.C.H., Standard enthalpies of formation of bis(trifluoroacetylacetonato)copper(II) and bis(hexafluoroacetylacetonato)copper(II): the mean (Cu«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1988, 20, 3, 359-361, https://doi.org/10.1016/0021-9614(88)90132-2 . [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru, Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor, Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022 . [all data]


Notes

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