bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper
- Formula: C10H8CuF6O4
- Molecular weight: 369.705
- CAS Registry Number: 14324-82-4
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 27.70 ± 0.57 | kcal/mol | N/A | Ribeiro da Silva, 1995 | |
| ΔsubH° | 27.96 ± 0.38 | kcal/mol | N/A | Ribeiro da Silva, 1995 | |
| ΔsubH° | 26.8 ± 0.72 | kcal/mol | C | Ribeiro da Silva and Ferrão, 1988 |
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 26.8 | 373. to 403. | TGA | Fahlman and Barron, 2000 | |
| 27.08 ± 0.57 | 350. | TE | Ribeiro da Silva, 1995 | Based on data from 342. to 359. K. |
| 27.34 ± 0.38 | 350. | ME | Ribeiro da Silva, 1995 | Based on data from 342. to 359. K. |
| 26.3 ± 0.2 | 383. to 463. | GS | Matsubara and Kuwamoto, 1985 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ribeiro da Silva, 1995
Ribeiro da Silva, M.,
Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) β-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014
. [all data]
Ribeiro da Silva and Ferrão, 1988
Ribeiro da Silva, Manuel A.V.; Ferrão, Maria Luisa C.C.H.,
Standard enthalpies of formation of bis(trifluoroacetylacetonato)copper(II) and bis(hexafluoroacetylacetonato)copper(II): the mean (Cu«58872»O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1988, 20, 3, 359-361, https://doi.org/10.1016/0021-9614(88)90132-2
. [all data]
Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R.,
Substituent effects on the volatility of metal ?-diketonates,
Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M
. [all data]
Matsubara and Kuwamoto, 1985
Matsubara, Norio; Kuwamoto, Tooru,
Vapor pressures and enthalpies of sublimation and evaporation of trifluoroacetylacetonates in helium and helium containing the ligand vapor,
Inorg. Chem., 1985, 24, 17, 2697-2701, https://doi.org/10.1021/ic00211a022
. [all data]
Notes
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- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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