1-Decanethiol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-276.4 ± 1.4kJ/molCcrGood and DePrater, 1966ALS
Quantity Value Units Method Reference Comment
Δcliquid-7405.1 ± 1.2kJ/molCcrGood and DePrater, 1966ALS
Quantity Value Units Method Reference Comment
liquid476.13J/mol*KN/AFinke, McCullough, et al., 1970DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
365.44300.Tutubalina, Gabdrakhmanov, et al., 1982T = 273 to 373 K. Cp = 346.70 + 3.600x10-2T + 8.824x10-5T2.; DH
350.41298.15Finke, McCullough, et al., 1970T = 10 to 370 K.; DH
349.63298.15Good and DePrater, 1966DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple247.87KN/AFinke, McCullough, et al., 1970, 2Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple247.850KN/AFinke, McCullough, et al., 1970, 2Uncertainty assigned by TRC = 0.005 K; TRC
Quantity Value Units Method Reference Comment
Δvap65.48kJ/molN/AMajer and Svoboda, 1985 
Δvap65.48 ± 0.54kJ/molCMansson, Sellers, et al., 1977ALS
Δvap65.5 ± 0.5kJ/molCMånsson, Sellers, et al., 1977AC
Δvap64.5 ± 0.4kJ/molEGood and DePrater, 1966ALS
Δvap64.5kJ/molN/AGood and DePrater, 1966DRB

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
387.20.017Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
56.4405.N/ADykyj, Svoboda, et al., 1999Based on data from 390. to 544. K.; AC
58.6288.AStephenson and Malanowski, 1987Based on data from 283. to 293. K.; AC
54.6428.AStephenson and Malanowski, 1987Based on data from 413. to 534. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
33.317247.86Finke, McCullough, et al., 1970DH
33.3247.9Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
134.42247.86Finke, McCullough, et al., 1970DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Decanethiol = 1-Decanethiol

By formula: C10H22S = C10H22S

Quantity Value Units Method Reference Comment
Δr-33.38 ± 0.02kJ/molCmFinke, McCullough, et al., 1970liquid phase; Heat of solidification

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good and DePrater, 1966
Good, W.D.; DePrater, B.L., The enthalpies of combustion and formation of the 1-alkanethiols. The methylene increment to the enthalpy of formation, J. Phys. Chem., 1966, 70, 3606-3609. [all data]

Finke, McCullough, et al., 1970
Finke, H.L.; McCullough, J.P.; Messerly, J.F.; Gutherie, G.B.; Douslin, D.R., Chemical thermodynamic properties for 1-alkanethiols, J. Chem. Thermodyn., 1970, 2, 27-41. [all data]

Tutubalina, Gabdrakhmanov, et al., 1982
Tutubalina, V.P.; Gabdrakhmanov, F.G.; Konyukhova, T.M., Study of the heat capacity of n-sulfides, 1982, Teplo-Massoobmen Khim. [all data]

Finke, McCullough, et al., 1970, 2
Finke, H.L.; McCullough, J.P.; Messerly, J.F.; Guthrie, G.B.; Douslin, D.R., Chemical thermodynamic properties for 1-alkanethiols, J. Chem. Thermodyn., 1970, 2, 27. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Mansson, Sellers, et al., 1977
Mansson, M.; Sellers, P.; Stridh, G.; Sunner, S., Enthalpies of vaporization of some 1-substituted n-alkanes, J. Chem. Thermodyn., 1977, 9, 91. [all data]

Månsson, Sellers, et al., 1977
Månsson, M.; Sellers, P.; Stridh, G.; Sunner, S., Enthalpies of vaporization of some 1-substituted n-alkanes, The Journal of Chemical Thermodynamics, 1977, 9, 1, 91-97, https://doi.org/10.1016/0021-9614(77)90202-6 . [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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