Dirhenium decacarbonyl


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-372.2 ± 2.2kcal/molReviewMartinho Simões 
Δfgas-369.0 ± 1.5kcal/molReviewMartinho Simões 
Δfgas-372.06 ± 0.93kcal/molReviewMartinho Simões 
Δfgas-372.8 ± 3.4kcal/molReviewMartinho Simões 
Δfgas-371.5 ± 1.7kcal/molReviewMartinho SimõesSelected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-396.3 ± 2.1kcal/molReviewMartinho Simões 
Δfsolid-393.2 ± 1.5kcal/molReviewMartinho Simões 
Δfsolid-396.18 ± 0.81kcal/molReviewMartinho Simões 
Δfsolid-396.9 ± 3.4kcal/molReviewMartinho Simões 
Δfsolid-395.6 ± 1.7kcal/molReviewMartinho SimõesSelected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983
Quantity Value Units Method Reference Comment
Δcsolid-857.91 ± 0.60kcal/molCC-SBChernova, Sheiman, et al., 1973Please also see Tel'noi and Rabinovich, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub24.1 ± 0.5kcal/molCC-SBAl-Takhin, Connor, et al., 1983Another literature value for the enthalpy of sublimation has been reported: 22.3 ± 1.0 kcal/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975; MS
Δsub24.1 ± 0.5kcal/molN/AAl-Takhin, Connor, et al., 1983, 2AC
Δsub22.3 ± 1.0kcal/molN/APilcher and Skinner, 1983See also Lalage, Brown, et al., 1974.; AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
16.4468.Baev, Dem'yanchuk, et al., 1971Based on data from 454. to 483. K.; AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
18.5406.MMBaev, Dem'yanchuk, et al., 1971Based on data from 363. to 450. K.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Chernova, Sheiman, et al., 1973
Chernova, V.I.; Sheiman, M.S.; Rabinovich, I.B.; Syrkin, V.G., Trudy Khim. Khim. Tekhnol., Gorky, 1973, No. 2, 43. [all data]

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]

Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A., J. Organomet. Chem., 1983, 259, 313. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M., J. Chem. Thermodyn., 1975, 7, 913. [all data]

Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A., Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives, Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A., The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds, Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1 . [all data]


Notes

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