Dirhenium decacarbonyl
- Formula: C10O10Re2
- Molecular weight: 652.515
- IUPAC Standard InChIKey: ZIZHEHXAMPQGEK-UHFFFAOYSA-N
- CAS Registry Number: 14285-68-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Re2(CO)10; Rhenium carbonyl; Rhenium, decacarbonyldi-,; Decacarbonyldirhenium; Rhenium carbonyl (Re2(CO)10); Rhenium, decacarbonyldi-, (Re-Re)
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -372.2 ± 2.2 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -369.0 ± 1.5 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -372.06 ± 0.93 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -372.8 ± 3.4 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -371.5 ± 1.7 | kcal/mol | Review | Martinho Simões | Selected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -396.3 ± 2.1 | kcal/mol | Review | Martinho Simões | |
ΔfH°solid | -393.2 ± 1.5 | kcal/mol | Review | Martinho Simões | |
ΔfH°solid | -396.18 ± 0.81 | kcal/mol | Review | Martinho Simões | |
ΔfH°solid | -396.9 ± 3.4 | kcal/mol | Review | Martinho Simões | |
ΔfH°solid | -395.6 ± 1.7 | kcal/mol | Review | Martinho Simões | Selected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983 |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -857.91 ± 0.60 | kcal/mol | CC-SB | Chernova, Sheiman, et al., 1973 | Please also see Tel'noi and Rabinovich, 1977. |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 24.1 ± 0.5 | kcal/mol | CC-SB | Al-Takhin, Connor, et al., 1983 | Another literature value for the enthalpy of sublimation has been reported: 22.3 ± 1.0 kcal/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975; MS |
ΔsubH° | 24.1 ± 0.5 | kcal/mol | N/A | Al-Takhin, Connor, et al., 1983, 2 | AC |
ΔsubH° | 22.3 ± 1.0 | kcal/mol | N/A | Pilcher and Skinner, 1983 | See also Lalage, Brown, et al., 1974.; AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
16.4 | 468. | Baev, Dem'yanchuk, et al., 1971 | Based on data from 454. to 483. K.; AC |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
18.5 | 406. | MM | Baev, Dem'yanchuk, et al., 1971 | Based on data from 363. to 450. K.; AC |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Chernova, Sheiman, et al., 1973
Chernova, V.I.; Sheiman, M.S.; Rabinovich, I.B.; Syrkin, V.G.,
Trudy Khim. Khim. Tekhnol., Gorky, 1973, No. 2, 43. [all data]
Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y.,
High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir,
Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018
. [all data]
Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A.,
J. Organomet. Chem., 1983, 259, 313. [all data]
Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. Chem. Rev., 1977, 46, 689. [all data]
Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A.,
J. Organometal. Chem., 1974, 81, 403. [all data]
Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E.,
Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]
Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M.,
J. Chem. Thermodyn., 1975, 7, 913. [all data]
Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A.,
Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives,
Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4
. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A.,
The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds,
Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1
. [all data]
Notes
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- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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