Dirhenium decacarbonyl
- Formula: C10O10Re2
- Molecular weight: 652.515
- IUPAC Standard InChIKey: ZIZHEHXAMPQGEK-UHFFFAOYSA-N
- CAS Registry Number: 14285-68-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Re2(CO)10; Rhenium carbonyl; Rhenium, decacarbonyldi-,; Decacarbonyldirhenium; Rhenium carbonyl (Re2(CO)10); Rhenium, decacarbonyldi-, (Re-Re)
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 101. ± 2. | kJ/mol | CC-SB | Al-Takhin, Connor, et al., 1983 | Another literature value for the enthalpy of sublimation has been reported: 93.3 ± 4.2 kJ/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975; MS |
ΔsubH° | 101. ± 2. | kJ/mol | N/A | Al-Takhin, Connor, et al., 1983, 2 | AC |
ΔsubH° | 93.3 ± 4.2 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Lalage, Brown, et al., 1974.; AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
68.7 | 468. | Baev, Dem'yanchuk, et al., 1971 | Based on data from 454. to 483. K.; AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
77.6 | 406. | MM | Baev, Dem'yanchuk, et al., 1971 | Based on data from 363. to 450. K.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A.,
J. Organomet. Chem., 1983, 259, 313. [all data]
Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A.,
J. Organometal. Chem., 1974, 81, 403. [all data]
Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E.,
Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]
Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M.,
J. Chem. Thermodyn., 1975, 7, 913. [all data]
Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A.,
Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives,
Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4
. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A.,
The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds,
Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1
. [all data]
Notes
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- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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