Dirhenium decacarbonyl
- Formula: C10O10Re2
- Molecular weight: 652.515
- IUPAC Standard InChI: InChI=1S/10CO.2Re/c10*1-2;;
- IUPAC Standard InChIKey: ZIZHEHXAMPQGEK-UHFFFAOYSA-N
- CAS Registry Number: 14285-68-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Re2(CO)10; Rhenium carbonyl; Rhenium, decacarbonyldi-,; Decacarbonyldirhenium; Rhenium carbonyl (Re2(CO)10); Rhenium, decacarbonyldi-, (Re-Re)
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -372.2 ± 2.2 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | -369.0 ± 1.5 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | -372.06 ± 0.93 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | -372.8 ± 3.4 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | -371.5 ± 1.7 | kcal/mol | Review | Martinho Simões | Selected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983 |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -396.3 ± 2.1 | kcal/mol | Review | Martinho Simões | |
| ΔfH°solid | -393.2 ± 1.5 | kcal/mol | Review | Martinho Simões | |
| ΔfH°solid | -396.18 ± 0.81 | kcal/mol | Review | Martinho Simões | |
| ΔfH°solid | -396.9 ± 3.4 | kcal/mol | Review | Martinho Simões | |
| ΔfH°solid | -395.6 ± 1.7 | kcal/mol | Review | Martinho Simões | Selected data. Average of the values from Chernova, Sheiman, et al., 1973, Connor, Skinner, et al., 1973, and Al-Takhin, Connor, et al., 1983 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -857.91 ± 0.60 | kcal/mol | CC-SB | Chernova, Sheiman, et al., 1973 | Please also see Tel'noi and Rabinovich, 1977. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 24.1 ± 0.5 | kcal/mol | CC-SB | Al-Takhin, Connor, et al., 1983 | Another literature value for the enthalpy of sublimation has been reported: 22.3 ± 1.0 kcal/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975; MS |
| ΔsubH° | 24.1 ± 0.5 | kcal/mol | N/A | Al-Takhin, Connor, et al., 1983, 2 | AC |
| ΔsubH° | 22.3 ± 1.0 | kcal/mol | N/A | Pilcher and Skinner, 1983 | See also Lalage, Brown, et al., 1974.; AC |
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 16.4 | 468. | Baev, Dem'yanchuk, et al., 1971 | Based on data from 454. to 483. K.; AC |
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 18.5 | 406. | MM | Baev, Dem'yanchuk, et al., 1971 | Based on data from 363. to 450. K.; AC |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(solution) +
(solution) = 2C10MnO10Re (solution)
By formula: C10Mn2O10 (solution) + C10O10Re2 (solution) = 2C10MnO10Re (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 28.9 ± 7.4 | kcal/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane; The reaction enthalpy was calculated from the enthalpies of the following reactions: Mn2(CO)10(solution) + I2(solution) = 2Mn(CO)5(I)(solution), -44.9 ± 2.0 kcal/mol, Re2(CO)10(solution) + I2(solution) = 2Re(CO)5(I)(solution), -37.6 ± 3.8 kcal/mol, and MnRe(CO)10(solution) + I2(solution) = Mn(CO)5(I)(solution) + Re(CO)5(I)(solution), -55.7 ± 3.0 kcal/mol |
| ΔrH° | 8.22 ± 0.31 | kcal/mol | EqS | Marcomini and Poë, 1984 | solvent: Decalin; Temperature range: 443-463 K |
(solution) = 2C5O5Re (solution)
By formula: C10O10Re2 (solution) = 2C5O5Re (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | >39.7 | kcal/mol | KinS | Marcomini and Poë, 1984 | solvent: Decalin; Please also see Poë, 1981. The reaction enthalpy was derived from the enthalpy of activation, 39.6 ± 0.2 kcal/mol Poë, 1981, by assuming a negligible barrier for the radical recombination. This procedure was later considered to yield a low limit of the reaction enthalpy Poë, 1983 Marcomini and Poë, 1984 Marcomini and Poë, 1983 Coville, Stolzenberg, et al., 1983. See also Schmidt, Trogler, et al., 1984 |
(cr) +
(cr) = 2
(cr)
By formula: C10O10Re2 (cr) + I2 (cr) = 2C5IO5Re (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -41.1 ± 4.3 | kcal/mol | PC | Harel and Adamson, 1986 | The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -37.6 ± 3.8 kcal/mol, and from the solution enthalpies of Re2(CO)10(cr), 8.20 ± 0.50 kcal/mol, I2(cr), 4.90 ± 0.1 kcal/mol, and Re(CO)5(I)(cr), 8.3 ± 1.0 kcal/mol Harel and Adamson, 1986 |
(solution) +
(solution) = 2
(solution)
By formula: C10O10Re2 (solution) + I2 (solution) = 2C5IO5Re (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -37.6 ± 3.8 | kcal/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane; Please also see Adamson, Vogler, et al., 1978. |
(cr) = 10
(g) + 2
(cr)
By formula: C10O10Re2 (cr) = 10CO (g) + 2Re (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 129.0 ± 1.4 | kcal/mol | TD-HFC | Connor, Skinner, et al., 1973 | |
| ΔrH° | 132.0 ± 0.72 | kcal/mol | HAL-HFC | Connor, Skinner, et al., 1973 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Chernova, Sheiman, et al., 1973
Chernova, V.I.; Sheiman, M.S.; Rabinovich, I.B.; Syrkin, V.G.,
Trudy Khim. Khim. Tekhnol., Gorky, 1973, No. 2, 43. [all data]
Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y.,
High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir,
Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018
. [all data]
Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A.,
J. Organomet. Chem., 1983, 259, 313. [all data]
Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. Chem. Rev., 1977, 46, 689. [all data]
Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A.,
J. Organometal. Chem., 1974, 81, 403. [all data]
Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E.,
Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]
Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M.,
J. Chem. Thermodyn., 1975, 7, 913. [all data]
Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A.,
Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives,
Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4
. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A.,
The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds,
Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1
. [all data]
Harel and Adamson, 1986
Harel, Y.; Adamson, A.W.,
J. Phys. Chem., 1986, 90, 6693. [all data]
Marcomini and Poë, 1984
Marcomini, A.; Poë, A.,
J. Chem. Soc., Dalton Trans., 1984, 95.. [all data]
Poë, 1981
Poë, A.,
ACS Symp. Ser., 1981, No. 155, 135. [all data]
Poë, 1983
Poë, A.,
Chem. Brit., 1983, 19, 997. [all data]
Marcomini and Poë, 1983
Marcomini, A.; Poë, A.,
J. Am. Chem. Soc., 1983, 105, 6952. [all data]
Coville, Stolzenberg, et al., 1983
Coville, N.J.; Stolzenberg, A.M.; Muetterties, E.L.,
J. Am. Chem. Soc., 1983, 105, 2499. [all data]
Schmidt, Trogler, et al., 1984
Schmidt, S.P.; Trogler, W.C.; Basolo, F.,
J. Am. Chem. Soc., 1984, 106, 1308. [all data]
Adamson, Vogler, et al., 1978
Adamson, A.W.; Vogler, A.; Kunkely, H.; Wachter, R.,
J. Am. Chem. Soc., 1978, 100, 1298. [all data]
Notes
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- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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