1-Propanamine, N-propyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-116.5 ± 1.6kJ/molCcbRibeiro da Silva, Ribeiro da Silva, et al., 1997ALS
Δfgas-118.1kJ/molN/ALebedeva, Katin, et al., 1971Value computed using ΔfHliquid° value of -156.2±0.4 kj/mol from Lebedeva, Katin, et al., 1971 and ΔvapH° value of 38.1 kj/mol from Ribeiro da Silva, Ribeiro da Silva, et al., 1997.; DRB

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-154.6 ± 1.5kJ/molCcbRibeiro da Silva, Ribeiro da Silva, et al., 1997 
Δfliquid-156.2 ± 0.42kJ/molCcbLebedeva, Katin, et al., 1971 
Quantity Value Units Method Reference Comment
Δcliquid-4350.2 ± 1.3kJ/molCcbRibeiro da Silva, Ribeiro da Silva, et al., 1997 
Δcliquid-4348.68 ± 0.42kJ/molCcbLebedeva, Katin, et al., 1971 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil383. ± 2.KAVGN/AAverage of 13 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus209.6KN/AAnonymous, 1958Uncertainty assigned by TRC = 0.6 K; TRC
Tfus210.15KN/ATimmermans and Mattaar, 1921Uncertainty assigned by TRC = 0.5 K; TRC
Tfus233.55KN/ATimmermans, 1921Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tc555.8KN/AToczylkin. L.S. and Young, 1980Uncertainty assigned by TRC = 0.55 K; TRC
Quantity Value Units Method Reference Comment
Pc36.30barN/AToczylkin. L.S. and Young, 1980Uncertainty assigned by TRC = 0.3627 bar; Visual; TRC
Quantity Value Units Method Reference Comment
Δvap40. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
33.47382.4N/AMajer and Svoboda, 1985 
40.0336.N/AResa, González, et al., 2000Based on data from 321. to 382. K.; AC
39.8317.AStephenson and Malanowski, 1987Based on data from 302. to 422. K. See also Dykyj, 1972.; AC
41.291.VLebedeva, Katin, et al., 1971ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + C6H13N = 1-Propanamine, N-propyl-

By formula: H2 + C6H13N = C6H15N

Quantity Value Units Method Reference Comment
Δr80.8 ± 0.8kJ/molChydJackman and Packham, 1957liquid phase; solvent: bis-2-Ethoxyethyl ether

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
19. MN/A

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Ribeiro da Silva, et al., 1997
Ribeiro da Silva, M.A.V.; Ribeiro da Silva, M.D.M.C.; Luisa, M.; Gomes, A.C.N.; Johnson, M.; Pilcher, G., Enthalpies of combustion of di-n-propylamine, diisopropylamine, diisobutylamine, and di-sec-butylamine, J. Chem. Thermodyn., 1997, 29, 1025-1030. [all data]

Lebedeva, Katin, et al., 1971
Lebedeva, N.D.; Katin, Y.A.; Akhmedova, G.Y., Enthalpies of formation of dipropylamine, di-isopropylamine, dibutylamine, and di-isobutylamine, Russ. J. Phys. Chem. (Engl. Transl.), 1971, 45, 771-772. [all data]

Anonymous, 1958
Anonymous, R., , Am. Pet. Inst. Res. Proj. 45, Ohio State Univ., 1958. [all data]

Timmermans and Mattaar, 1921
Timmermans, J.; Mattaar, J.F., Freezing points of orgainic substances VI. New experimental determinations., Bull. Soc. Chim. Belg., 1921, 30, 213. [all data]

Timmermans, 1921
Timmermans, J., The Freezing Points of Organic Substances IV. New Exp. Determinations, Bull. Soc. Chim. Belg., 1921, 30, 62. [all data]

Toczylkin. L.S. and Young, 1980
Toczylkin. L.S.; Young, C.L., Gas-liquid criticl temperatures of mixtures containing electron donors. II. Amine mixtures, J. Chem. Thermodyn., 1980, 12, 365. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Resa, González, et al., 2000
Resa, José M.; González, Cristina; Ortiz de Landaluce, Salomé; Lanz, Juan, Vapor-Liquid Equilibrium of Binary Mixtures Containing Diethylamine + Diisopropylamine, Diethylamine + Dipropylamine, and Chloroform + Diisopropylamine at 101.3 kPa, and Vapor Pressures of Dipropylamine, J. Chem. Eng. Data, 2000, 45, 5, 867-871, https://doi.org/10.1021/je000020g . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Jackman and Packham, 1957
Jackman, L.M.; Packham, D.I., The experimental resonance energy of acridine, Proc. Chem. Soc., London, 1957, 349-350. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, References