Helium cation
- Formula: He+
- Molecular weight: 4.002053
- CAS Registry Number: 14234-48-1
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 31.527 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1982 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (He+ • He) + He = (He+ • 2He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.2 | kcal/mol | DT | Patterson, 1968 | gas phase; corrected for ln T term |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.4 | cal/mol*K | DT | Patterson, 1968 | gas phase; corrected for ln T term |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
-1.9 | 300. | SAMS | Gusinow, Gerber, et al., 1970 | gas phase |
By formula: (He+ • 2He) + He = (He+ • 3He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.73 ± 0.15 | kcal/mol | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.7 | cal/mol*K | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.6 | 77. | DT | Helm, 1976 | gas phase |
By formula: (He+ • 3He) + He = (He+ • 4He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.64 ± 0.15 | kcal/mol | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 12.8 | cal/mol*K | PHPMS | Hiraoka and Mori, 1990 | gas phase |
By formula: (He+ • 4He) + He = (He+ • 5He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.48 ± 0.15 | kcal/mol | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 10.8 | cal/mol*K | PHPMS | Hiraoka and Mori, 1990 | gas phase |
By formula: He+ + He = (He+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.5 | kcal/mol | EmSpec | Dehmer and Pratt, 1982 | gas phase |
ΔrH° | 58.8 | kcal/mol | SCATTERING | Mittman and Weise, 1974 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Patterson, 1968
Patterson, P.L.,
Evidence of the Existence of an He3+ Ion,
J. Chem. Phys., 1968, 48, 8, 3625, https://doi.org/10.1063/1.1669660
. [all data]
Gusinow, Gerber, et al., 1970
Gusinow, M.A.; Gerber, R.A.; Gerardo, J.B.,
He3+ and He4+ in 300K Helium Plasmas: Their Effect on Recombination Loss of Electrons,
Phys. Rev. Lett., 1970, 25, 18, 1248, https://doi.org/10.1103/PhysRevLett.25.1248
. [all data]
Hiraoka and Mori, 1990
Hiraoka, K.; Mori, T.,
Stability of Rare - Gas Cluster Ions,
J. Chem. Phys., 1990, 92, 7, 4408, https://doi.org/10.1063/1.457751
. [all data]
Helm, 1976
Helm, H.,
The Mobilities and Equilibrium Reactions of Helium Ions in Helium at 77K,
J. Phys. B, 1976, 9, 7, 1171, https://doi.org/10.1088/0022-3700/9/7/017
. [all data]
Dehmer and Pratt, 1982
Dehmer, P.M.; Pratt, S.T.,
Photoionization of ArKr, ArXe, and KrXe and bond dissociation energies of the rare gas dimer ions,
J. Chem. Phys., 1982, 77, 4804. [all data]
Mittman and Weise, 1974
Mittman, H.U.; Weise, H.P.,
Scattering of Ions V. Elastic Scattering of the Symmetric Rare Gas Ion - Rare Gas Atom Systems,
Z. Naturforsch., 1974, A29, 400. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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