D-Glucitol, 6TMS derivative

• Formula: C₂₄H₆₂O₆Si₆
• Molecular weight: 615.2585
• IUPAC Standard InChI: InChI=1S/C24H62O6Si6/c1-31(2,3)25-19-21(27-33(7,8)9)23(29-35(13,14)15)24(30-36(16,17)18)22(28-34(10,11)12)20-26-32(4,5)6/h21-24H,19-20H2,1-18H3/t21-,22+,23-,24-/m1/s1 Copy

  
• IUPAC Standard InChIKey: USBJDBWAPKNPCK-UEQSERJNSA-N Copy
• CAS Registry Number: 14199-80-5
• Chemical structure:
  This structure is also available as a 2d Mol file
• Stereoisomers:
  • D-Mannitol, 6TMS derivative
  • Galactitol, 6TMS derivative
  • D-Mannitol, TMS
  • Sorbitol, hexakis-TMS
  • Allitol, TMS
  • L-Sorbitol TMS
  • Altritol, TMS
  • Iditol, TMS
  • D-Sorbitol, 6TMS derivative
• Other names: Trimethylsilyl ether of glucitol; d-Glucitol, 1,2,3,4,5,6-hexakis-O-(trimethylsilyl)-; Glucitol, hexakis-O-(trimethylsilyl)-, d-; 1,2,3,4,5,6-Hexakis-O-(trimethylsilyl)glucitol; D-Glucitol, hexakis-TMS; Glucitol, hexakis-TMS; Sorbitol, hexakis-O-(trimethylsilyl)-ether; Sorbitol, (6TMS); Sorbitol, TMS; Glucitol, TMS; D-Glucitol, TMS; D-Sorbitol (Glucitol), TMS
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• Information on this page:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Kovats' RI, non-polar column, temperature ramp

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Normal alkane RI, non-polar column, isothermal

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Normal alkane RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adam, 1981
Adam, S., Separation of mono- and di-saccharide derivatives by high-resolution gas chromatography, Z. Lebensm. Unters. Forsch., 1981, 173, 2, 109-112, https://doi.org/10.1007/BF01042273 . [all data]

Medeiros and Simoneit, 2007
Medeiros, P.M.; Simoneit, B.R.T., Analysis of sugars in environmental samples by gas chromatography-mass spectrometry, J. Chromatogr. A, 2007, 1141, 2, 271-278, https://doi.org/10.1016/j.chroma.2006.12.017 . [all data]

Jonsson, Johansson, et al., 2005
Jonsson, P.; Johansson, A.I.; Gullberg, J.; Trygg, J.; Jiye, A.; Grung, B.; Marklund, S.; Sjöström, M.; Antti, H.; Moritz, T., High-throughput data analysis for detecting and identifying differences between samples in GC/MS-based metabolomic analyses, Anal. Chem., 2005, 77, 17, 5635-5642, https://doi.org/10.1021/ac050601e . [all data]

Wagner, Sefkow, et al., 2003
Wagner, C.; Sefkow, M.; Kopka, J., Construction and application of a mass spectral and retention time index database generated from plant GC/EI-TOF-MS metabolite profiles, Phytochemistry, 2003, 62, 6, 887-900, https://doi.org/10.1016/S0031-9422(02)00703-3 . [all data]

Madaj, Wisniewski, et al., 1993
Madaj, J.; Wisniewski, A.; Skorupowa, E.; Sokolowski, J., Capillary gas chromatographic separations of a multicomponent mixture of polyalcohol compounds, J. Chromatogr. A, 1993, 655, 2, 267-273, https://doi.org/10.1016/0021-9673(93)83232-H . [all data]

Zegota, 1980
Zegota, H., Separation and quantitative determination of fructose as the O-methyloxime by gas-liquid chromatography using glass capillary columns, J. Chromatogr., 1980, 192, 2, 446-451, https://doi.org/10.1016/S0021-9673(80)80024-0 . [all data]

Isidorov, Lech, et al., 2008
Isidorov, V.A.; Lech, P.; Zolciak, A.; Rusak, N.; Szczepaniak, L., Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack, Trees, 2008, 22, 4, 531-542, https://doi.org/10.1007/s00468-008-0213-z . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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