Arabinitol, 5TMS derivative
- Formula: C20H52O5Si5
- Molecular weight: 513.0514
- IUPAC Standard InChI: InChI=1S/C20H52O5Si5/c1-26(2,3)21-16-18(23-28(7,8)9)20(25-30(13,14)15)19(24-29(10,11)12)17-22-27(4,5)6/h18-20H,16-17H2,1-15H3/t18-,19-/m1/s1
- IUPAC Standard InChIKey: SUZLPERYXSOGNY-RTBURBONSA-N
- CAS Registry Number: 14199-73-6
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: Arabitol, pentakis(trimethylsilyl)-; 1,2,3,4,5-Pentakis-O-(trimethylsilyl)arabitol; Arabinitol, pentakis-TMS; Arabitol (5TMS); Arabitol, TMS; Arabinitol, TMS
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | O A MAMER, MCGILL UNIVERSITY, MONTRE |
| NIST MS number | 79245 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | OV-101 | 200. | 1758.7 | Adam, 1981 | Column length: 50. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5MS | 1702.3 | Jonsson, Johansson, et al., 2005 | 10. m/0.18 mm/0.18 μm, 70. C @ 2. min, 40. K/min, 320. C @ 2. min |
| Capillary | DB-5MS | 1718.9 | Jonsson, Johansson, et al., 2005 | 10. m/0.18 mm/0.18 μm, 70. C @ 2. min, 40. K/min, 320. C @ 2. min |
| Capillary | DB-5 | 1737. | Fu, Iga, et al., 2000 | 30. m/0.25 mm/0.25 μm, He, 100. C @ 1. min, 10. K/min, 290. C @ 8. min |
| Capillary | DB-5 | 1776. | Fu, Iga, et al., 2000 | 30. m/0.25 mm/0.25 μm, He, 100. C @ 1. min, 10. K/min, 290. C @ 8. min |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1760. | Madaj, Wisniewski, et al., 1993 | H2; Column length: 50. m; Column diameter: 0.20 mm; Program: 115 0C 3 0C/min -> 180 0C 4 0C/min -> 250 0C |
| Capillary | DB-1 | 1748. | Yang and Cashman, 1992 | 30. m/0.32 mm/1.0 μm, He; Program: 3 min at 100 0C; 100 - 200 0C at 8 deg/min; 1 min at 200 0C; 200 - 280 0C at 5 deg/min; 30 min at 280 0C |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adam, 1981
Adam, S.,
Separation of mono- and di-saccharide derivatives by high-resolution gas chromatography,
Z. Lebensm. Unters. Forsch., 1981, 173, 2, 109-112, https://doi.org/10.1007/BF01042273
. [all data]
Jonsson, Johansson, et al., 2005
Jonsson, P.; Johansson, A.I.; Gullberg, J.; Trygg, J.; Jiye, A.; Grung, B.; Marklund, S.; Sjöström, M.; Antti, H.; Moritz, T.,
High-throughput data analysis for detecting and identifying differences between samples in GC/MS-based metabolomic analyses,
Anal. Chem., 2005, 77, 17, 5635-5642, https://doi.org/10.1021/ac050601e
. [all data]
Fu, Iga, et al., 2000
Fu, X.; Iga, M.; Kimura, M.; Yamaguchi, S.,
Simplified screening for organic acidemia using GC/MS and dried urine filter paper: a study on neonatal mass screening,
Early Hum. Dev., 2000, 58, 1, 41-55, https://doi.org/10.1016/S0378-3782(00)00053-0
. [all data]
Madaj, Wisniewski, et al., 1993
Madaj, J.; Wisniewski, A.; Skorupowa, E.; Sokolowski, J.,
Capillary gas chromatographic separations of a multicomponent mixture of polyalcohol compounds,
J. Chromatogr. A, 1993, 655, 2, 267-273, https://doi.org/10.1016/0021-9673(93)83232-H
. [all data]
Yang and Cashman, 1992
Yang, Z.C.; Cashman, J.R.,
Structure-retention index relationships for derivatized monosaccharides on non-polar gas chromatography columns,
J. Chromatogr., 1992, 596, 1, 79-84, https://doi.org/10.1016/0021-9673(92)80205-9
. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
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