Arabinitol, 5TMS derivative
- Formula: C20H52O5Si5
- Molecular weight: 513.0514
- IUPAC Standard InChI: InChI=1S/C20H52O5Si5/c1-26(2,3)21-16-18(23-28(7,8)9)20(25-30(13,14)15)19(24-29(10,11)12)17-22-27(4,5)6/h18-20H,16-17H2,1-15H3/t18-,19-/m1/s1
- IUPAC Standard InChIKey: SUZLPERYXSOGNY-RTBURBONSA-N
- CAS Registry Number: 14199-73-6
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: Arabitol, pentakis(trimethylsilyl)-; 1,2,3,4,5-Pentakis-O-(trimethylsilyl)arabitol; Arabinitol, pentakis-TMS; Arabitol (5TMS); Arabitol, TMS; Arabinitol, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | OV-101 | 200. | 1758.7 | Adam, 1981 | Column length: 50. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5MS | 1702.3 | Jonsson, Johansson, et al., 2005 | 10. m/0.18 mm/0.18 μm, 70. C @ 2. min, 40. K/min, 320. C @ 2. min |
| Capillary | DB-5MS | 1718.9 | Jonsson, Johansson, et al., 2005 | 10. m/0.18 mm/0.18 μm, 70. C @ 2. min, 40. K/min, 320. C @ 2. min |
| Capillary | DB-5 | 1737. | Fu, Iga, et al., 2000 | 30. m/0.25 mm/0.25 μm, He, 100. C @ 1. min, 10. K/min, 290. C @ 8. min |
| Capillary | DB-5 | 1776. | Fu, Iga, et al., 2000 | 30. m/0.25 mm/0.25 μm, He, 100. C @ 1. min, 10. K/min, 290. C @ 8. min |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1760. | Madaj, Wisniewski, et al., 1993 | H2; Column length: 50. m; Column diameter: 0.20 mm; Program: 115 0C 3 0C/min -> 180 0C 4 0C/min -> 250 0C |
| Capillary | DB-1 | 1748. | Yang and Cashman, 1992 | 30. m/0.32 mm/1.0 μm, He; Program: 3 min at 100 0C; 100 - 200 0C at 8 deg/min; 1 min at 200 0C; 200 - 280 0C at 5 deg/min; 30 min at 280 0C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adam, 1981
Adam, S.,
Separation of mono- and di-saccharide derivatives by high-resolution gas chromatography,
Z. Lebensm. Unters. Forsch., 1981, 173, 2, 109-112, https://doi.org/10.1007/BF01042273
. [all data]
Jonsson, Johansson, et al., 2005
Jonsson, P.; Johansson, A.I.; Gullberg, J.; Trygg, J.; Jiye, A.; Grung, B.; Marklund, S.; Sjöström, M.; Antti, H.; Moritz, T.,
High-throughput data analysis for detecting and identifying differences between samples in GC/MS-based metabolomic analyses,
Anal. Chem., 2005, 77, 17, 5635-5642, https://doi.org/10.1021/ac050601e
. [all data]
Fu, Iga, et al., 2000
Fu, X.; Iga, M.; Kimura, M.; Yamaguchi, S.,
Simplified screening for organic acidemia using GC/MS and dried urine filter paper: a study on neonatal mass screening,
Early Hum. Dev., 2000, 58, 1, 41-55, https://doi.org/10.1016/S0378-3782(00)00053-0
. [all data]
Madaj, Wisniewski, et al., 1993
Madaj, J.; Wisniewski, A.; Skorupowa, E.; Sokolowski, J.,
Capillary gas chromatographic separations of a multicomponent mixture of polyalcohol compounds,
J. Chromatogr. A, 1993, 655, 2, 267-273, https://doi.org/10.1016/0021-9673(93)83232-H
. [all data]
Yang and Cashman, 1992
Yang, Z.C.; Cashman, J.R.,
Structure-retention index relationships for derivatized monosaccharides on non-polar gas chromatography columns,
J. Chromatogr., 1992, 596, 1, 79-84, https://doi.org/10.1016/0021-9673(92)80205-9
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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