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3-Penten-2-one, 4-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil403. ± 1.KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus226.75KN/AAnonymous, 1968TRC
Tfus220.3KN/AStross, Monger, et al., 1947Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tc605.KN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc40.00barN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 1.50 bar; derived from fit of obs. vapor pressure; TRC
Quantity Value Units Method Reference Comment
rhoc2.830mol/lN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 0.10 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap42.70 ± 0.28kJ/molVSteele, Chirico, et al., 1997, 2ALS
Deltavap42.7 ± 0.3kJ/molEBSteele, Chirico, et al., 1997, 3Based on data from 303. - 442. K.; AC
Deltavap44.8kJ/molCGCChickos, Hosseini, et al., 1995Based on data from 343. - 383. K.; AC
Deltavap43.3kJ/molN/AMesserly, Finke, et al., 1975Based on data from 292. - 471. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
41.4 ± 0.3320.EBSteele, Chirico, et al., 1997, 3Based on data from 303. - 442. K.; AC
39.1 ± 0.3360.EBSteele, Chirico, et al., 1997, 3Based on data from 303. - 442. K.; AC
36.5 ± 0.3400.EBSteele, Chirico, et al., 1997, 3Based on data from 303. - 442. K.; AC
33.5 ± 0.6440.EBSteele, Chirico, et al., 1997, 3Based on data from 303. - 442. K.; AC
37.8414.AStephenson and Malanowski, 1987Based on data from 399. - 471. K.; AC
41.5328.MMStephenson and Malanowski, 1987Based on data from 313. - 405. K. See also Stross, Monger, et al., 1947, 2 and Dykyj, 1972.; AC
35.2401.N/ALouguinine, 1898May be a mixture of 2-methyl-1-penten-4-one and 4-methyl-3-penten-2-one; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
287. - 403.14.193531434.631-60.088Fuge, Bowden, et al., 1952Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
12.1229.6Borgen, Borgen, et al., 1975AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Anonymous, 1968
Anonymous, X., Chemicals and Plastics Physical Properties, 1968, Union Carbide Corp., product bulletin, 1968. [all data]

Stross, Monger, et al., 1947
Stross, F.H.; Monger, J.M.; Finch, H. deV., Isolation and Purification of the Two Isomers of Mesityl Oxide, J. Am. Chem. Soc., 1947, 69, 1627-8. [all data]

Steele, Chirico, et al., 1997
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A., Thermodynamic Properties and Ideal-Gas Enthalpies of FOrmation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, (Z)-5-Ethylidene-2- norbornene, Mesityl Oxide (4-Methyl-3-pentene-2-one), 4-M, J. Chem. Eng. Data, 1997, 42, 1053-66. [all data]

Steele, Chirico, et al., 1997, 2
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A., Thermodynamic properties and ideal-gas enthalpies of formation for 2-aminoisobutyric acid (2-methylalanine), acetic acid, (4-methyl-3-penten-2-one), 4-methylpent-1-ene, 2,2'-bis(phenylthio)propane, and glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane), J. Chem. Eng. Data, 1997, 42, 1052-1066. [all data]

Steele, Chirico, et al., 1997, 3
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A., Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, ( Z )-5-Ethylidene-2-norbornene, Mesityl Oxide (4-Methyl-3-penten-2-one), 4-Methylpent-1-ene, 2,2'-Bis(phenylthio)propane, and Glycidyl Phenyl Ether (1,2-Epoxy-3-phenoxypropane), J. Chem. Eng. Data, 1997, 42, 6, 1053-1066, https://doi.org/10.1021/je970099y . [all data]

Chickos, Hosseini, et al., 1995
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G., Determination of vaporization enthalpies of simple organic molecules by correlations of changes in gas chromatographic net retention times, Thermochimica Acta, 1995, 249, 41-62, https://doi.org/10.1016/0040-6031(95)90670-3 . [all data]

Messerly, Finke, et al., 1975
Messerly, J.F.; Finke, H.L.; Osborn, A.G.; Douslin, D.R., Low-temperature calorimetric and vapor-pressure studies on alkanediamines, J. Chem. Thermodynam., 1975, 7, 1029-1046. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stross, Monger, et al., 1947, 2
Stross, F.H.; Monger, J.M.; Finch, H. de V., The Isolation and Purification of Two Isomers of Mesityl Oxide, J. Am. Chem. Soc., 1947, 69, 7, 1627-1628, https://doi.org/10.1021/ja01199a016 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Louguinine, 1898
Louguinine, W., Ann. Chim. (Paris), 1898, 7, 334. [all data]

Fuge, Bowden, et al., 1952
Fuge, E.T.J.; Bowden, S.T.; Jones, W.J., Some Physical Properties of Diacetone Alcohol, Mesityl Oxide and Methyl Isobutyl Ketone, J. Phys. Chem., 1952, 56, 8, 1013-1016, https://doi.org/10.1021/j150500a022 . [all data]

Borgen, Borgen, et al., 1975
Borgen, Gerd; Borgen, Gerd; Dale, Johannes; Gaupset, Gudmund; Schroll, G.; Altona, C., Syntheses and Conformations of Monomeric and Dimeric Cyclic Dimethylketals., Acta Chem. Scand., 1975, 29b, 265-272, https://doi.org/10.3891/acta.chem.scand.29b-0265 . [all data]


Notes

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