Tetratriacontane
- Formula: C34H70
- Molecular weight: 478.9196
- IUPAC Standard InChIKey: GWVDBZWVFGFBCN-UHFFFAOYSA-N
- CAS Registry Number: 14167-59-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: n-Tetratriacontane
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
1149. | 353. | Atkinson, Larkin, et al., 1969 | T = 353 to 453 K. Equation only. |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
887.4 | 303. | Garner, Van Bibber, et al., 1931 | T = 293 to 373 K. Mean value 20 to 40°C. β-form. |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 346.0 ± 0.7 | K | AVG | N/A | Average of 16 out of 17 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 172.7 | kJ/mol | CGC | Chickos and Hanshaw, 2004 | Based on data from 534. to 565. K.; AC |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference | Comment |
---|---|---|---|
558.2 | 0.003 | Aldrich Chemical Company Inc., 1990 | BS |
558.6 | 0.004 | Weast and Grasselli, 1989 | BS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
152. ± 2. | 471. | TE | Piacente, Fontana, et al., 1994 | Based on data from 446. to 497. K.; AC |
149.7 | 387. | A | Stephenson and Malanowski, 1987 | Based on data from 372. to 402. K.; AC |
120.3 | 538. | A,E | Stephenson and Malanowski, 1987 | Based on data from 523. to 756. K. See also Kudchadker and Zwolinski, 1966.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
95.64 | 346.1 | DSC | Wang, Tozaki, et al., 2006 | AC |
79.96 | 345.9 | N/A | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
85.8 | 341.5 | Acree, 1993 | CAL |
231.1 | 345.9 |
Temperature of phase transition
Ttrs (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|
342.25 | crystaline, III | crystaline, II | Company, 1973 | DH |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
48.032 | 342.65 | crystaline, II | crystaline, I | Company, 1973 | DH |
79.956 | 345.95 | crystaline, I | liquid | Company, 1973 | DH |
48.032 | 341.1 | crystaline, II | crystaline, I | Garner, Van Bibber, et al., 1931 | DH |
79.956 | 345.6 | crystaline, I | liquid | Garner, Van Bibber, et al., 1931 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
140.2 | 342.65 | crystaline, II | crystaline, I | Company, 1973 | DH |
231.1 | 345.95 | crystaline, I | liquid | Company, 1973 | DH |
140.8 | 341.1 | crystaline, II, á | crystaline, I, à transition | Garner, Van Bibber, et al., 1931 | DH |
231.4 | 345.6 | crystaline, I | liquid | Garner, Van Bibber, et al., 1931 | DH |
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-2326 |
NIST MS number | 234130 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Atkinson, Larkin, et al., 1969
Atkinson, C.M.L.; Larkin, J.A.; Richardson, M.J.,
Enthalpy changes in molten n-alkanes and polyethylene,
J. Chem. Thermodynam., 1969, 1, 435-445. [all data]
Garner, Van Bibber, et al., 1931
Garner, W.E.; Van Bibber, K.; King, A.M.,
The melting points and heats of crystallization of the normal long-chain hydrocarbons,
J. Chem. Soc. (London), 1931, 1931, 1533-1541. [all data]
Chickos and Hanshaw, 2004
Chickos, James S.; Hanshaw, William,
Vapor Pressures and Vaporization Enthalpies of the n -Alkanes from C 31 to C 38 at T = 298.15 K by Correlation Gas Chromatography,
J. Chem. Eng. Data, 2004, 49, 3, 620-630, https://doi.org/10.1021/je030236t
. [all data]
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Piacente, Fontana, et al., 1994
Piacente, Vincenzo; Fontana, Danilo; Scardala, Paolo,
Enthalpies of Vaporization of a Homologous Series of n-Alkanes Determined from Vapor Pressure Measurements,
J. Chem. Eng. Data, 1994, 39, 2, 231-237, https://doi.org/10.1021/je00014a009
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Kudchadker and Zwolinski, 1966
Kudchadker, A.P.; Zwolinski, B.J.,
Vapor Pressure and Boiling Points of Normal Alkanes, C 21 to C 100 .,
J. Chem. Eng. Data, 1966, 11, 2, 253-255, https://doi.org/10.1021/je60029a039
. [all data]
Wang, Tozaki, et al., 2006
Wang, Shaolan; Tozaki, Ken-Ichi; Hayashi, Hideko; Inaba, Hideaki; Yamamoto, Hiroko,
Observation of multiple phase transitions in some even n-alkanes using a high resolution and super-sensitive DSC,
Thermochimica Acta, 2006, 448, 2, 73-81, https://doi.org/10.1016/j.tca.2006.06.022
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Acree, 1993
Acree, W.E., Jr.,
Thermodynamic properties of organic compounds,
Thermochim. Acta, 1993, 219, 97, https://doi.org/10.1016/0040-6031(93)80486-T
. [all data]
Company, 1973
Company, J.C.,
Measurement and interpretation of crystallization equilibriums of heavy paraffin and aromatic hydrocarbon solutions,
Chem. Eng. Sci., 1973, 28, 318-323. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid Tboil Boiling point Tfus Fusion (melting) point Ttrs Temperature of phase transition ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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