Nitrogen cation
- Formula: N+
- Molecular weight: 14.0062
- CAS Registry Number: 14158-23-7
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
N+ + = (N+ •
)
By formula: N+ + N2 = (N+ • N2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 249. | kJ/mol | N/A | National Bureau of Standards, 1968 | gas phase; from ΔrH(f) |
| ΔrH° | 250. | kJ/mol | EI | Saporoschenko, 1965 | gas phase |
| ΔrH° | 250. | kJ/mol | EI | Franklin, Dibeler, et al., 1958 | gas phase |
Enthalpy of reaction
| ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 361. (+7.5,-0.) | CID | Haynes, Freysinger, et al., 1995 | gas phase; guided ion beam CID |
N+ + = (N+ •
)
By formula: N+ + Ar = (N+ • Ar)
Enthalpy of reaction
| ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 118. (+44.,-0.) | CID | Haynes, Freysinger, et al., 1995 | gas phase; giuded ion beam CID |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
National Bureau of Standards, 1968
National Bureau of Standards, US,
Technical Note 270 - 3
in The NBS Tables of Chemical Thermodynamic Properties, 1968. [all data]
Saporoschenko, 1965
Saporoschenko, M.,
Mobility of Mass Analyzed N+, N2+, N3+, and N4+ Ions in Nitrogen Gas,
Phys. Rev. A, 1965, 139, 352. [all data]
Franklin, Dibeler, et al., 1958
Franklin, J.L.; Dibeler, V.H.; Reese, R.M.; Krauss, M.,
Ionization and dissociation of hydrazoic acid and methyl azide by electron impact,
J. Am. Chem. Soc., 1958, 80, 298. [all data]
Haynes, Freysinger, et al., 1995
Haynes, C.L.; Freysinger, W.; Armentrout, P.B.,
Collision-induced dissociation of N3+(X3-) with Ne, Ar, Kr, and Xe,
Int. J. Mass Spectrom. Ion Processes, 1995, 149/150, 267. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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