Nitrogen cation
- Formula: N+
- Molecular weight: 14.0062
- CAS Registry Number: 14158-23-7
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Clustering reactions
N+ + = (N+ •
)
By formula: N+ + Ar = (N+ • Ar)
Enthalpy of reaction
| ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 28. (+11.,-0.) | CID | Haynes, Freysinger, et al., 1995 | gas phase; giuded ion beam CID |
N+ + = (N+ •
)
By formula: N+ + N2 = (N+ • N2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 59.4 | kcal/mol | N/A | National Bureau of Standards, 1968 | gas phase; from ΔrH(f) |
| ΔrH° | 60. | kcal/mol | EI | Saporoschenko, 1965 | gas phase |
| ΔrH° | 59. | kcal/mol | EI | Franklin, Dibeler, et al., 1958 | gas phase |
Enthalpy of reaction
| ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 86.2 (+1.8,-0.) | CID | Haynes, Freysinger, et al., 1995 | gas phase; guided ion beam CID |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Haynes, Freysinger, et al., 1995
Haynes, C.L.; Freysinger, W.; Armentrout, P.B.,
Collision-induced dissociation of N3+(X3-) with Ne, Ar, Kr, and Xe,
Int. J. Mass Spectrom. Ion Processes, 1995, 149/150, 267. [all data]
National Bureau of Standards, 1968
National Bureau of Standards, US,
Technical Note 270 - 3
in The NBS Tables of Chemical Thermodynamic Properties, 1968. [all data]
Saporoschenko, 1965
Saporoschenko, M.,
Mobility of Mass Analyzed N+, N2+, N3+, and N4+ Ions in Nitrogen Gas,
Phys. Rev. A, 1965, 139, 352. [all data]
Franklin, Dibeler, et al., 1958
Franklin, J.L.; Dibeler, V.H.; Reese, R.M.; Krauss, M.,
Ionization and dissociation of hydrazoic acid and methyl azide by electron impact,
J. Am. Chem. Soc., 1958, 80, 298. [all data]
Notes
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- Symbols used in this document:
T Temperature ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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