Manganese ion (1+)

• Formula: Mn⁺
• Molecular weight: 54.937496
• IUPAC Standard InChI: InChI=1S/Mn/q+1 Copy

  
• IUPAC Standard InChIKey: LIASWTUFJMBWEN-UHFFFAOYSA-N Copy
• CAS Registry Number: 14127-69-6
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Manganese cation
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Ion clustering data
  • References
  • Notes
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = ( • )

By formula: Mn⁺ + Mn = (Mn⁺ • Mn)

 +  = ( • )

By formula: Mn⁺ + H₂O = (Mn⁺ • H₂O)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + C₆H₆ = (Mn⁺ • C₆H₆)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • CO) + CO = (Mn⁺ • 2CO)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2CO) + CO = (Mn⁺ • 3CO)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3CO) + CO = (Mn⁺ • 4CO)

Enthalpy of reaction

( • 4) +  = ( • 5)

By formula: (Mn⁺ • 4CO) + CO = (Mn⁺ • 5CO)

Enthalpy of reaction

( • 5) +  = ( • 6)

By formula: (Mn⁺ • 5CO) + CO = (Mn⁺ • 6CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • H₂O) + H₂O = (Mn⁺ • 2H₂O)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + CO = (Mn⁺ • CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₆H₆) + C₆H₆ = (Mn⁺ • 2C₆H₆)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2H₃N) + H₃N = (Mn⁺ • 3H₃N)

( • ) +  = ( • 2)

By formula: (Mn⁺ • H₃N) + H₃N = (Mn⁺ • 2H₃N)

 +  = ( • )

By formula: Mn⁺ + H₃N = (Mn⁺ • H₃N)

 +  = ( • )

By formula: Mn⁺ + CS = (Mn⁺ • CS)

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2H₂O) + H₂O = (Mn⁺ • 3H₂O)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3H₂O) + H₂O = (Mn⁺ • 4H₂O)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3H₃N) + H₃N = (Mn⁺ • 4H₃N)

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₂H₄) + C₂H₄ = (Mn⁺ • 2C₂H₄)

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₄H₅N) + C₄H₅N = (Mn⁺ • 2C₄H₅N)

 +  = ( • )

By formula: Mn⁺ + C₅H₅N = (Mn⁺ • C₅H₅N)

 +  = ( • )

By formula: Mn⁺ + CH₃ = (Mn⁺ • CH₃)

 +  = ( • )

By formula: Mn⁺ + C₃D₆O = (Mn⁺ • C₃D₆O)

 +  = ( • )

By formula: Mn⁺ + C₄H₄N₂ = (Mn⁺ • C₄H₄N₂)

 +  = ( • )

By formula: Mn⁺ + C₅H₅N₅ = (Mn⁺ • C₅H₅N₅)

 +  = ( • )

By formula: Mn⁺ + C₂H₄ = (Mn⁺ • C₂H₄)

 +  = ( • )

By formula: Mn⁺ + C₃H₆O = (Mn⁺ • C₃H₆O)

 +  = ( • )

By formula: Mn⁺ + C₄H₅N = (Mn⁺ • C₄H₅N)

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Mn⁺ + CH₃ = (Mn⁺ • CH₃)

 +  = ( • )

By formula: Mn⁺ + CO = (Mn⁺ • CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • CO) + CO = (Mn⁺ • 2CO)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2CO) + CO = (Mn⁺ • 3CO)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3CO) + CO = (Mn⁺ • 4CO)

Enthalpy of reaction

( • 4) +  = ( • 5)

By formula: (Mn⁺ • 4CO) + CO = (Mn⁺ • 5CO)

Enthalpy of reaction

( • 5) +  = ( • 6)

By formula: (Mn⁺ • 5CO) + CO = (Mn⁺ • 6CO)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + CS = (Mn⁺ • CS)

 +  = ( • )

By formula: Mn⁺ + C₂H₄ = (Mn⁺ • C₂H₄)

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₂H₄) + C₂H₄ = (Mn⁺ • 2C₂H₄)

 +  = ( • )

By formula: Mn⁺ + C₃D₆O = (Mn⁺ • C₃D₆O)

 +  = ( • )

By formula: Mn⁺ + C₃H₆O = (Mn⁺ • C₃H₆O)

 +  = ( • )

By formula: Mn⁺ + C₄H₄N₂ = (Mn⁺ • C₄H₄N₂)

 +  = ( • )

By formula: Mn⁺ + C₄H₅N = (Mn⁺ • C₄H₅N)

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₄H₅N) + C₄H₅N = (Mn⁺ • 2C₄H₅N)

 +  = ( • )

By formula: Mn⁺ + C₅H₅N = (Mn⁺ • C₅H₅N)

 +  = ( • )

By formula: Mn⁺ + C₅H₅N₅ = (Mn⁺ • C₅H₅N₅)

 +  = ( • )

By formula: Mn⁺ + C₆H₆ = (Mn⁺ • C₆H₆)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₆H₆) + C₆H₆ = (Mn⁺ • 2C₆H₆)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + H₂O = (Mn⁺ • H₂O)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • H₂O) + H₂O = (Mn⁺ • 2H₂O)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2H₂O) + H₂O = (Mn⁺ • 3H₂O)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3H₂O) + H₂O = (Mn⁺ • 4H₂O)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + H₃N = (Mn⁺ • H₃N)

( • ) +  = ( • 2)

By formula: (Mn⁺ • H₃N) + H₃N = (Mn⁺ • 2H₃N)

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2H₃N) + H₃N = (Mn⁺ • 3H₃N)

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3H₃N) + H₃N = (Mn⁺ • 4H₃N)

 +  = ( • )

By formula: Mn⁺ + Mn = (Mn⁺ • Mn)

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Houriet and Vulpius, 1989
Houriet, R.; Vulpius, T., Formation of Metal Cluster Ions by Gas - Phase Ion - Molecule Reactions: the Bond Energies of Cr2+ and Mn2+, Chem. Phys. Lett., 1989, 154, 5, 454, https://doi.org/10.1016/0009-2614(89)87130-1 . [all data]

Jarrold, Illies, et al., 1985
Jarrold, M.F.; Illies, A.J.; Wagner-Redeker, W.; Bowers, M.T., Photodissociation of Weakly Bound Ion - Molecule Clusters: The Kr.CO2+ Cluster, J. Phys. Chem., 1985, 89, 15, 3269, https://doi.org/10.1021/j100261a020 . [all data]

Ervin, Loh, et al., 1983
Ervin, K.; Loh, S.K.; Aristov, N.; Armentrout, P.B., Metal cluster ions: The bond energy of Mn₂⁺, J. Phys. Chem., 1983, 87, 3593. [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Lin, Chen, et al., 1997
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Observing Unimolecular Dissociation of Metastable Ions in FT-ICR: A Novel Application of the Continuous Ejection Technique, J. Phys. Chem. A, 1997, 101, 34, 6023, https://doi.org/10.1021/jp970446a . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Dearden, Hayashibara, et al., 1989
Dearden, D.V.; Hayashibara, K.; Beauchamp, J.L.; Kirschner, N.J.; Van Koppen, P.A.M.; Bowers, M.T., Fundamental Studies of the Energetics and Dynamics of Ligand Dissociation and Exchange Processes at Transition - Metal Centers in the Gas Phase: Mn(COx)+, x = 1 - 6, J. Am. Chem. Soc., 1989, 111, 7, 2401, https://doi.org/10.1021/ja00189a005 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Georgiadis and Armentrout, 1989
Georgiadis, R.; Armentrout, P.B., Translational and Electronic Energy Dependence of the Reaction of Mn+ with Ethane, Int. J. Mass Spectrom. Ion Proc., 1989, 91, 2, 123, https://doi.org/10.1016/0168-1176(89)83003-4 . [all data]

Lin, Chen, et al., 1997, 2
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Bond Dissociation Energy Determinations for MOC(CH3)2+ and MOC(CD3)2+ (M=Cr, Mn) Using Continuous Ejection and Radiative Association Methods, Int. J. Mass Spectrom. Ion Proc., 1997, 167/168, 713, https://doi.org/10.1016/S0168-1176(97)00131-6 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  T	Temperature
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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