2-(Methylsulphonyl)-2-methylpropane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-473. ± 4.kJ/molCcrBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-556. ± 3.kJ/molCcrBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure
Quantity Value Units Method Reference Comment
Δcsolid-3728.9 ± 2.3kJ/molCcrBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus357.KN/AKaldor and Hammond, 1991Uncertainty assigned by TRC = 2. K; TRC
Tfus357.6KN/ABusfield, Ivin, et al., 1961Uncertainty assigned by TRC = 0.5 K; TRC
Tfus357.6KN/ABusfield, Mackle, et al., 1961, 2Uncertainty assigned by TRC = 1. K; TRC
Tfus351.KN/AHu and Chen, 1958Uncertainty assigned by TRC = 4. K; TRC
Tfus350.KN/ARheinboldt, Mott, et al., 1932Uncertainty assigned by TRC = 6. K; TRC
Quantity Value Units Method Reference Comment
Δsub82. ± 3.kJ/molEBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure; ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
24.69357.6Busfield, Ivin, et al., 1961AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Busfield, Mackle, et al., 1961
Busfield, W.K.; Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 2 - The standard heats of formation of sulphones of the type RSO2CH3, Trans. Faraday Soc., 1961, 57, 1054-1057. [all data]

Kaldor and Hammond, 1991
Kaldor, S.W.; Hammond, M., A Mild Osmium Tetraoxide-Catalyzed Method for the Oxidation of Sulfides to Sulfones, Tetrahedron Lett., 1991, 32, 5043-6. [all data]

Busfield, Ivin, et al., 1961
Busfield, W.K.; Ivin, K.J.; Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 3.?Fusion and vaporization heats of sulphones of the type RSO2CH3, Trans. Faraday Soc., 1961, 57, 1058, https://doi.org/10.1039/tf9615701058 . [all data]

Busfield, Mackle, et al., 1961, 2
Busfield, W.K.; Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 2.- The standard heats of formation of sulphones of the type RSO2CH3, Trans. Faraday Soc., 1961, 57, 1054. [all data]

Hu and Chen, 1958
Hu, P.-F.; Chen, W.-Y., Organophosphorous Compounds IV. The Anomalous Reaction of Some Alcohls with Phosphorous Pentasulfide, Hua Hsueh Hsueh Pao, 1958, 24, 112-6. [all data]

Rheinboldt, Mott, et al., 1932
Rheinboldt, H.; Mott, F.; Motzlus, E., Tertiary Butyl Mercapatan, J. Prakt. Chem., 1932, 134, 257. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References