Piperazine, 1,4-dinitroso-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid22.2 ± 0.5kcal/molCcbPepekin, Matyushin, et al., 1974 
Quantity Value Units Method Reference Comment
Δcsolid-671.7 ± 0.5kcal/molCcbPepekin, Matyushin, et al., 1974 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus429.15KN/AAroney and Le Fevre, 1960Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Δsub24.2 ± 0.2kcal/molVPepekin, Matyushin, et al., 1974ALS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
24. ± 2.343.Pepekin, Matyushin, et al., 1974Based on data from 325. to 360. K. See also Pedley and Rylance, 1977.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pepekin, Matyushin, et al., 1974
Pepekin, V.I.; Matyushin, Yu.N.; Lebedev, Yu.A., Thermochemistry of N-nitro- and N-nitrosoamines of the alicyclic series, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1974, 1707-1710. [all data]

Aroney and Le Fevre, 1960
Aroney, M.; Le Fevre, R.J.W., Molecular polarizability. The conformation of various n-substituted anilines, piperidines, and piperazines, J. Chem. Soc., 1960, 1960, 2161. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]


Notes

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