Zinc, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]-, (SP-4-1)-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub46.8 ± 0.7kcal/molMEPatiño, Campos, et al., 2002Based on data from 555. to 567. K.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
43.7 ± 0.7559.MEPatiño, Campos, et al., 2002Based on data from 555. to 567. K.
50.9 ± 0.7563. to 663.N/APerlovich, Naneishvili, et al., 1994See also Patiño, Campos, et al., 2002.
26.1666.UV/VisEdwards, Dolphin, et al., 1971See also Patiño, Campos, et al., 2002.

UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Fajer, et al., 1970
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 15928
Instrument Cary 14

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Patiño, Campos, et al., 2002
Patiño, Rodrigo; Campos, Myriam; Torres, Luis Alfonso, A thermochemical study of 5,10,15,20-tetraphenylporphine zinc(II) by rotating bomb combustion calorimetry and by Knudsen effusion experiments, The Journal of Chemical Thermodynamics, 2002, 34, 2, 193-204, https://doi.org/10.1006/jcht.2001.0911 . [all data]

Perlovich, Naneishvili, et al., 1994
Perlovich, G.L.; Naneishvili, B.K.; Golubchikov, O.A., Thermodynamic characteristics of sublimation of tetraphenylporphyrin metal complexes, Zh. Fiz. Khim., 1994, 68, 11, 1932. [all data]

Edwards, Dolphin, et al., 1971
Edwards, L.; Dolphin, D.H.; Gouterman, M.; Adler, A.D., Porphyrins XVII. Vapor absorption spectra and redox reactions: Tetraphenylporphins and porphin, Journal of Molecular Spectroscopy, 1971, 38, 1, 16-32, https://doi.org/10.1016/0022-2852(71)90090-7 . [all data]

Fajer, et al., 1970
Fajer, J., et al., J. Am. Chem. Soc., 1970, 92, 3451. [all data]


Notes

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