Carbon cation


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar154.66J/mol*KReviewChase, 1998Data last reviewed in March, 1983

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Carbon cation + Carbon = (Carbon cation • Carbon)

By formula: C+ + C = (C+ • C)

Quantity Value Units Method Reference Comment
ΔrH°619. ± 50.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • Carbon) + Carbon = (Carbon cation • 2Carbon)

By formula: (C+ • C) + C = (C+ • 2C)

Quantity Value Units Method Reference Comment
ΔrH°774. ± 67.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 2Carbon) + Carbon = (Carbon cation • 3Carbon)

By formula: (C+ • 2C) + C = (C+ • 3C)

Quantity Value Units Method Reference Comment
ΔrH°598.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 3Carbon) + Carbon = (Carbon cation • 4Carbon)

By formula: (C+ • 3C) + C = (C+ • 4C)

Quantity Value Units Method Reference Comment
ΔrH°695.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 4Carbon) + Carbon = (Carbon cation • 5Carbon)

By formula: (C+ • 4C) + C = (C+ • 5C)

Quantity Value Units Method Reference Comment
ΔrH°628.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 5Carbon) + Carbon = (Carbon cation • 6Carbon)

By formula: (C+ • 5C) + C = (C+ • 6C)

Quantity Value Units Method Reference Comment
ΔrH°745.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 6Carbon) + Carbon = (Carbon cation • 7Carbon)

By formula: (C+ • 6C) + C = (C+ • 7C)

Quantity Value Units Method Reference Comment
ΔrH°649.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering
ΔrH°523.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 7Carbon) + Carbon = (Carbon cation • 8Carbon)

By formula: (C+ • 7C) + C = (C+ • 8C)

Quantity Value Units Method Reference Comment
ΔrH°753.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering

(Carbon cation • 8Carbon) + Carbon = (Carbon cation • 9Carbon)

By formula: (C+ • 8C) + C = (C+ • 9C)

Quantity Value Units Method Reference Comment
ΔrH°703.kJ/molMSPargellis, 1990gas phase; equilibrium cluster distributions from sputtering
ΔrH°745. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 9Carbon) + Carbon = (Carbon cation • 10Carbon)

By formula: (C+ • 9C) + C = (C+ • 10C)

Quantity Value Units Method Reference Comment
ΔrH°732. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 2Carbon) + Dicarbon = (Carbon cation • Dicarbon • 2Carbon)

By formula: (C+ • 2C) + C2 = (C+ • C2 • 2C)

Quantity Value Units Method Reference Comment
ΔrH°745.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 2Carbon) + Tricarbon = (Carbon cation • Tricarbon • 2Carbon)

By formula: (C+ • 2C) + C3 = (C+ • C3 • 2C)

Quantity Value Units Method Reference Comment
ΔrH°531.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 3Carbon) + Tricarbon = (Carbon cation • Tricarbon • 3Carbon)

By formula: (C+ • 3C) + C3 = (C+ • C3 • 3C)

Quantity Value Units Method Reference Comment
ΔrH°502.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 4Carbon) + Tricarbon = (Carbon cation • Tricarbon • 4Carbon)

By formula: (C+ • 4C) + C3 = (C+ • C3 • 4C)

Quantity Value Units Method Reference Comment
ΔrH°502.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 5Carbon) + Tricarbon = (Carbon cation • Tricarbon • 5Carbon)

By formula: (C+ • 5C) + C3 = (C+ • C3 • 5C)

Quantity Value Units Method Reference Comment
ΔrH°510.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 6Carbon) + Tricarbon = (Carbon cation • Tricarbon • 6Carbon)

By formula: (C+ • 6C) + C3 = (C+ • C3 • 6C)

Quantity Value Units Method Reference Comment
ΔrH°695. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

(Carbon cation • 7Carbon) + Tricarbon = (Carbon cation • Tricarbon • 7Carbon)

By formula: (C+ • 7C) + C3 = (C+ • C3 • 7C)

Quantity Value Units Method Reference Comment
ΔrH°724. ± 96.kJ/molMIKESRadi, Rincon, et al., 1989gas phase

References

Go To: Top, Gas phase thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Pargellis, 1990
Pargellis, A.N., Estimating Carbon Cluster Binding Energies from Measured Cn Distributions, n <= 10, J. Chem. Phys., 1990, 93, 3, 2099, https://doi.org/10.1063/1.459035 . [all data]

Radi, Rincon, et al., 1989
Radi, P.P.; Rincon, M.E.; Hsu, M.T.; Brodbelt-Lustig, J.; Kemper, P.; Bowers, M.T., Structure, Reactivity and Energetics of Covalently Bound Carbon Cluster Ions, C5+ to C11+: Experiment and Theory, J. Phys. Chem., 1989, 93, 16, 6187, https://doi.org/10.1021/j100353a045 . [all data]


Notes

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