Chromium ion (1+)
- Formula: Cr+
- Molecular weight: 51.9956
- IUPAC Standard InChIKey: LCKHOIUMRVRUKY-UHFFFAOYSA-N
- CAS Registry Number: 14067-03-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Chromium cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 51 to 79
- Ion clustering data
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: Cr+ + Cr = (Cr+ • Cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 150. ± 20. | kJ/mol | ICRCD | Houriet and Vulpius, 1989 | gas phase; M |
ΔrH° | 180. | kJ/mol | EI | Hilpert and Ruthardt, 1987 | gas phase; from IP(Cr2) by EI and D(Cr2) by Knudsen cell, and IP(Cr); M |
ΔrH° | 180. ± 20. | kJ/mol | KC-MS | Hilpert and Ruthardt, 1987 | gas phase; data as evaluated by Houriet and Vulpius, 1989; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
125. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • Ne) + Ne = (Cr+ • 2Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.6 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 3.8 kJ/mol, ΔrS(100 K) = 28. J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24. | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 3.8 kJ/mol, ΔrS(100 K) = 28. J/mol*K; M |
By formula: Cr+ + Ne = (Cr+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.8 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 5.77 kJ/mol, ΔrS(100 K) = 55.6 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 61.1 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 5.77 kJ/mol, ΔrS(100 K) = 55.6 J/mol*K; M |
By formula: Cr+ + Ar = (Cr+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29. ± 2. | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 27.4 kJ/mol, ΔrS(100 K) = 60.2 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 66.1 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 27.4 kJ/mol, ΔrS(100 K) = 60.2 J/mol*K; M |
By formula: Cr+ + He = (Cr+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.4 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 4.1 kJ/mol, ΔrS(100 K) = 55.6 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 61.9 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 4.1 kJ/mol, ΔrS(100 K) = 55.6 J/mol*K; M |
By formula: Cr+ + C6H6 = (Cr+ • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 168. | kJ/mol | MID | Lin, Chen, et al., 1997 | RCD |
ΔrH° | 164. ± 14. | kJ/mol | RAK | Lin and Dunbar, 1997 | RCD |
ΔrH° | 170. ± 10. | kJ/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
170. (+9.6,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: Cr+ + H2O = (Cr+ • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 120. ± 10. | kJ/mol | CID | Magnera, David, et al., 1989 | gas phase; M |
ΔrH° | 91.6 | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
129. (+9.2,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • C6H6) + C6H6 = (Cr+ • 2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 212. ± 38. | kJ/mol | RAK | Lin and Dunbar, 1997 | RCD |
ΔrH° | 232. ± 18. | kJ/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
231. (+18.,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • H2O) + H2O = (Cr+ • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 123. | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
142. (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C2H4 = (Cr+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 96. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
125. (+19.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: (Cr+ • 2CO) + CO = (Cr+ • 3CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.0 ± 5.9 | kJ/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
54.0 (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 3CO) + CO = (Cr+ • 4CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51.0 ± 7.5 | kJ/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.0 (+7.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 4CO) + CO = (Cr+ • 5CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62. ± 3. | kJ/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
62. (+3.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • CO) + CO = (Cr+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 95. ± 3. | kJ/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
95. (+3.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + CO = (Cr+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 90. ± 4. | kJ/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
90.0 (+4.2,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • H3N) + H3N = (Cr+ • 2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 179. ± 9.2 | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
ΔrH° | 171. | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: Cr+ + H3N = (Cr+ • H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 182. ± 10. | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
ΔrH° | 156. | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: Cr+ + CS = (Cr+ • CS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 163. ± 5.9 | kJ/mol | CIDT | Rue, Armentrout, et al., 2001 | RCD |
ΔrH° | 158. ± 9.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Cr+ • 3H2O) + H2O = (Cr+ • 4H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.0 (+7.1,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 2H2O) + H2O = (Cr+ • 3H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
50. (+50.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 5CO) + CO = (Cr+ • 6CO)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
130. (+7.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C6H2F4 = (Cr+ • C6H2F4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 103. | kJ/mol | RAK | Ryzhov, 1999 | RCD |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 5.2091×10+6 | J/mol*K | RAK | Ryzhov, 1999 | RCD |
By formula: Cr+ + C6H2F4 = (Cr+ • C6H2F4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 106. | kJ/mol | RAK | Ryzhov, 1999 | RCD |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 5.1672×10+6 | J/mol*K | RAK | Ryzhov, 1999 | RCD |
By formula: (Cr+ • 10Cr) + Cr = (Cr+ • 11Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
258. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 11Cr) + Cr = (Cr+ • 12Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
289. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 12Cr) + Cr = (Cr+ • 13Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
294. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 13Cr) + Cr = (Cr+ • 14Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
267. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 14Cr) + Cr = (Cr+ • 15Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
282. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 15Cr) + Cr = (Cr+ • 16Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
273. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 16Cr) + Cr = (Cr+ • 17Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
208. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 17Cr) + Cr = (Cr+ • 18Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
233. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 18Cr) + Cr = (Cr+ • 19Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
289. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 19Cr) + Cr = (Cr+ • 20Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
253. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 9Cr) + Cr = (Cr+ • 10Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
248. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 2Cr) + Cr = (Cr+ • 3Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
100. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 3Cr) + Cr = (Cr+ • 4Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
215. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 4Cr) + Cr = (Cr+ • 5Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
171. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 5Cr) + Cr = (Cr+ • 6Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
246. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 6Cr) + Cr = (Cr+ • 7Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
217. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 7Cr) + Cr = (Cr+ • 8Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
249. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 8Cr) + Cr = (Cr+ • 9Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
232. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • Cr) + Cr = (Cr+ • 2Cr)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
194. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C2H2 = (Cr+ • C2H2)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
184. (+20.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C3H4 = (Cr+ • C3H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. ± 8.4 | kJ/mol | CIDT | Fisher and Armentrout, 1992 | propyne or allene; RCD |
By formula: (Cr+ • 2H3N) + H3N = (Cr+ • 3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.0 ± 5.9 | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Cr+ • 3H3N) + H3N = (Cr+ • 4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. ± 9.2 | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Cr+ • C8H10) + C8H10 = (Cr+ • 2C8H10)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 212. ± 29. | kJ/mol | RAK | Lin and Dunbar, 1997 | RCD |
By formula: (Cr+ • C9H12) + C9H12 = (Cr+ • 2C9H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 212. ± 38. | kJ/mol | RAK | Lin and Dunbar, 1997 | RCD |
By formula: (Cr+ • C7H8) + C7H8 = (Cr+ • 2C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 222. ± 38. | kJ/mol | RAK | Lin and Dunbar, 1997 | RCD |
By formula: (Cr+ • C2H4) + C2H4 = (Cr+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 108. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Houriet and Vulpius, 1989
Houriet, R.; Vulpius, T.,
Formation of Metal Cluster Ions by Gas - Phase Ion - Molecule Reactions: the Bond Energies of Cr2+ and Mn2+,
Chem. Phys. Lett., 1989, 154, 5, 454, https://doi.org/10.1016/0009-2614(89)87130-1
. [all data]
Hilpert and Ruthardt, 1987
Hilpert, K.; Ruthardt, K.,
Determination of the dissociation energy of the Cr2 molecule,
Ber. Bunsen-Ges. Phys. Chem., 1987, 91, 724. [all data]
Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L.,
Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]
Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T.,
Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar),
J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022
. [all data]
Lin, Chen, et al., 1997
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S.,
Observing Unimolecular Dissociation of Metastable Ions in FT-ICR: A Novel Application of the Continuous Ejection Technique,
J. Phys. Chem. A, 1997, 101, 34, 6023, https://doi.org/10.1021/jp970446a
. [all data]
Lin and Dunbar, 1997
Lin, C.-Y.; Dunbar, R.C.,
Radiative Association Kinetics and Binding Energies of Chromium Ions with Benzene and Benzene Derivatives,
Organometallics, 1997, 16, 12, 2691, https://doi.org/10.1021/om960949n
. [all data]
Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B.,
Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu,
J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018
. [all data]
Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J.,
Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051
. [all data]
Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R.,
Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052
. [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B.,
Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes,
J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z
. [all data]
Khan, Clemmer, et al., 1993
Khan, F.A.; Clemmer, D.E.; Schultz, R.H.; Armentrout, P.B.,
Sequential Bond Energies of Cr(CO)x+, x=1-6,
J. Phys. Chem., 1993, 97, 30, 7978, https://doi.org/10.1021/j100132a029
. [all data]
Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B.,
Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD,
J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c
. [all data]
Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H.,
Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS,
Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Ryzhov, 1999
Ryzhov, V.,
Binding Energies of Chromium Cations with Fluorobenzenes from Radiative Association Kinetics,
Int. J. Mass Spectrom., 1999, 185/186/187, 913. [all data]
Fisher and Armentrout, 1992
Fisher, E.R.; Armentrout, P.B.,
Activation of Alkanes by Cr+: Unique Reactivity of Ground-State Cr+(6S) and Thermochemistry of Neutral and Ionic Chromium-Carbon Bonds,
J. Am. Chem. Soc., 1992, 114, 6, 2039, https://doi.org/10.1021/ja00032a017
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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