Chromium ion (1+)
- Formula: Cr+
- Molecular weight: 51.9956
- IUPAC Standard InChIKey: LCKHOIUMRVRUKY-UHFFFAOYSA-N
- CAS Registry Number: 14067-03-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Chromium cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 51 to 79
- Ion clustering data
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 41.355 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1984 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: Cr+ + Cr = (Cr+ • Cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 37. ± 5. | kcal/mol | ICRCD | Houriet and Vulpius, 1989 | gas phase; M |
ΔrH° | 42. | kcal/mol | EI | Hilpert and Ruthardt, 1987 | gas phase; from IP(Cr2) by EI and D(Cr2) by Knudsen cell, and IP(Cr); M |
ΔrH° | 43. ± 5. | kcal/mol | KC-MS | Hilpert and Ruthardt, 1987 | gas phase; data as evaluated by Houriet and Vulpius, 1989; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
29.9 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • Ne) + Ne = (Cr+ • 2Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.9 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 0.90 kcal/mol, ΔrS(100 K) = 6.8 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 5.7 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 0.90 kcal/mol, ΔrS(100 K) = 6.8 cal/mol*K; M |
By formula: Cr+ + Ne = (Cr+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 1.38 kcal/mol, ΔrS(100 K) = 13.3 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 14.6 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 1.38 kcal/mol, ΔrS(100 K) = 13.3 cal/mol*K; M |
By formula: Cr+ + Ar = (Cr+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.9 ± 0.4 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 6.55 kcal/mol, ΔrS(100 K) = 14.4 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 15.8 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 6.55 kcal/mol, ΔrS(100 K) = 14.4 cal/mol*K; M |
By formula: Cr+ + He = (Cr+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.3 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 0.98 kcal/mol, ΔrS(100 K) = 13.3 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 14.8 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 0.98 kcal/mol, ΔrS(100 K) = 13.3 cal/mol*K; M |
By formula: Cr+ + C6H6 = (Cr+ • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 40.2 | kcal/mol | MID | Lin, Chen, et al., 1997 | RCD |
ΔrH° | 39.2 ± 3.3 | kcal/mol | RAK | Lin and Dunbar, 1997 | RCD |
ΔrH° | 40.6 ± 2.4 | kcal/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
40.6 (+2.3,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: Cr+ + H2O = (Cr+ • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29. ± 3. | kcal/mol | CID | Magnera, David, et al., 1989 | gas phase; M |
ΔrH° | 21.9 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
30.8 (+2.2,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • C6H6) + C6H6 = (Cr+ • 2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50.7 ± 9.1 | kcal/mol | RAK | Lin and Dunbar, 1997 | RCD |
ΔrH° | 55.4 ± 4.3 | kcal/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
55.3 (+4.4,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • H2O) + H2O = (Cr+ • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29.5 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
33.9 (+1.4,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C2H4 = (Cr+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.9 ± 2.6 | kcal/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
29.9 (+4.5,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: (Cr+ • 2CO) + CO = (Cr+ • 3CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.9 ± 1.4 | kcal/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
12.9 (+1.4,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 3CO) + CO = (Cr+ • 4CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.2 ± 1.8 | kcal/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
12.2 (+1.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 4CO) + CO = (Cr+ • 5CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.8 ± 0.7 | kcal/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
14.8 (+0.7,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • CO) + CO = (Cr+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.6 ± 0.7 | kcal/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
22.7 (+0.7,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + CO = (Cr+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.4 ± 0.9 | kcal/mol | CIDT | Khan, Clemmer, et al., 1993 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
21.5 (+1.0,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • H3N) + H3N = (Cr+ • 2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.8 ± 2.2 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
ΔrH° | 40.8 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: Cr+ + H3N = (Cr+ • H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 43.5 ± 2.4 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
ΔrH° | 37.4 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: Cr+ + CS = (Cr+ • CS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 38.9 ± 1.4 | kcal/mol | CIDT | Rue, Armentrout, et al., 2001 | RCD |
ΔrH° | 37.8 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Cr+ • 3H2O) + H2O = (Cr+ • 4H2O)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
12.2 (+1.7,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 2H2O) + H2O = (Cr+ • 3H2O)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
12. (+12.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 5CO) + CO = (Cr+ • 6CO)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
31.0 (+1.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C6H2F4 = (Cr+ • C6H2F4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 24.6 | kcal/mol | RAK | Ryzhov, 1999 | RCD |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 1.2450×10+6 | cal/mol*K | RAK | Ryzhov, 1999 | RCD |
By formula: Cr+ + C6H2F4 = (Cr+ • C6H2F4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 25.4 | kcal/mol | RAK | Ryzhov, 1999 | RCD |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 1.2350×10+6 | cal/mol*K | RAK | Ryzhov, 1999 | RCD |
By formula: (Cr+ • 10Cr) + Cr = (Cr+ • 11Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
61.7 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 11Cr) + Cr = (Cr+ • 12Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
69.1 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 12Cr) + Cr = (Cr+ • 13Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
70.3 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 13Cr) + Cr = (Cr+ • 14Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
63.8 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 14Cr) + Cr = (Cr+ • 15Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.4 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 15Cr) + Cr = (Cr+ • 16Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
65.3 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 16Cr) + Cr = (Cr+ • 17Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
49.7 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 17Cr) + Cr = (Cr+ • 18Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
55.7 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 18Cr) + Cr = (Cr+ • 19Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
69.1 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 19Cr) + Cr = (Cr+ • 20Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
60.5 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 9Cr) + Cr = (Cr+ • 10Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
59.3 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 2Cr) + Cr = (Cr+ • 3Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
23.9 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 3Cr) + Cr = (Cr+ • 4Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.4 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 4Cr) + Cr = (Cr+ • 5Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
40.9 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 5Cr) + Cr = (Cr+ • 6Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
58.8 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 6Cr) + Cr = (Cr+ • 7Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.9 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 7Cr) + Cr = (Cr+ • 8Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
59.5 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • 8Cr) + Cr = (Cr+ • 9Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
55.4 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Cr+ • Cr) + Cr = (Cr+ • 2Cr)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
46.4 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C2H2 = (Cr+ • C2H2)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.0 (+4.8,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Cr+ + C3H4 = (Cr+ • C3H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.0 ± 2.0 | kcal/mol | CIDT | Fisher and Armentrout, 1992 | propyne or allene; RCD |
By formula: (Cr+ • 2H3N) + H3N = (Cr+ • 3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.9 ± 1.4 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Cr+ • 3H3N) + H3N = (Cr+ • 4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.2 ± 2.2 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Cr+ • C8H10) + C8H10 = (Cr+ • 2C8H10)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50.7 ± 6.9 | kcal/mol | RAK | Lin and Dunbar, 1997 | RCD |
By formula: (Cr+ • C9H12) + C9H12 = (Cr+ • 2C9H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50.7 ± 9.1 | kcal/mol | RAK | Lin and Dunbar, 1997 | RCD |
By formula: (Cr+ • C7H8) + C7H8 = (Cr+ • 2C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 53.1 ± 9.1 | kcal/mol | RAK | Lin and Dunbar, 1997 | RCD |
By formula: (Cr+ • C2H4) + C2H4 = (Cr+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 25.8 ± 2.6 | kcal/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Houriet and Vulpius, 1989
Houriet, R.; Vulpius, T.,
Formation of Metal Cluster Ions by Gas - Phase Ion - Molecule Reactions: the Bond Energies of Cr2+ and Mn2+,
Chem. Phys. Lett., 1989, 154, 5, 454, https://doi.org/10.1016/0009-2614(89)87130-1
. [all data]
Hilpert and Ruthardt, 1987
Hilpert, K.; Ruthardt, K.,
Determination of the dissociation energy of the Cr2 molecule,
Ber. Bunsen-Ges. Phys. Chem., 1987, 91, 724. [all data]
Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L.,
Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]
Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T.,
Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar),
J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022
. [all data]
Lin, Chen, et al., 1997
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S.,
Observing Unimolecular Dissociation of Metastable Ions in FT-ICR: A Novel Application of the Continuous Ejection Technique,
J. Phys. Chem. A, 1997, 101, 34, 6023, https://doi.org/10.1021/jp970446a
. [all data]
Lin and Dunbar, 1997
Lin, C.-Y.; Dunbar, R.C.,
Radiative Association Kinetics and Binding Energies of Chromium Ions with Benzene and Benzene Derivatives,
Organometallics, 1997, 16, 12, 2691, https://doi.org/10.1021/om960949n
. [all data]
Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B.,
Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu,
J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018
. [all data]
Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J.,
Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051
. [all data]
Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R.,
Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052
. [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B.,
Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes,
J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z
. [all data]
Khan, Clemmer, et al., 1993
Khan, F.A.; Clemmer, D.E.; Schultz, R.H.; Armentrout, P.B.,
Sequential Bond Energies of Cr(CO)x+, x=1-6,
J. Phys. Chem., 1993, 97, 30, 7978, https://doi.org/10.1021/j100132a029
. [all data]
Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B.,
Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD,
J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c
. [all data]
Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H.,
Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS,
Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Ryzhov, 1999
Ryzhov, V.,
Binding Energies of Chromium Cations with Fluorobenzenes from Radiative Association Kinetics,
Int. J. Mass Spectrom., 1999, 185/186/187, 913. [all data]
Fisher and Armentrout, 1992
Fisher, E.R.; Armentrout, P.B.,
Activation of Alkanes by Cr+: Unique Reactivity of Ground-State Cr+(6S) and Thermochemistry of Neutral and Ionic Chromium-Carbon Bonds,
J. Am. Chem. Soc., 1992, 114, 6, 2039, https://doi.org/10.1021/ja00032a017
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) T Temperature ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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