Aluminum hydride

• Formula: AlH
• Molecular weight: 27.98948
• IUPAC Standard InChI: InChI=1S/Al.H Copy

  
• IUPAC Standard InChIKey: SPRIOUNJHPCKPV-UHFFFAOYSA-N Copy
• CAS Registry Number: 13967-22-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Constants of diatomic molecules
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  =

By formula: Al^- + H⁺ = HAl

Constants of diatomic molecules

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through November, 1975

Notes

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Scheer, Bilodeau, et al., 1998
Scheer, M.; Bilodeau, RC; Thogresen, J.; Haugen, HK, Threshold Photodetachment of Al-: Electron Affinity and Fine Structure, Phys. Rev. A, 1998, 57, 3, R1493-, https://doi.org/10.1103/PhysRevA.57.R1493 . [all data]

Holst, 1933
Holst, W., Uber ein triplettbandenspektrum von aluminiumhydrid, Z. Phys., 1933, 86, 338. [all data]

Challacombe and Almy, 1937
Challacombe, C.N.; Almy, G.M., On the analysis of molecular ³Π states with application to AlH, OH⁺, and BH, Phys. Rev., 1937, 51, 930. [all data]

Holst, 1934
Holst, W., Uber ein neues bandenspektrum von aluminiumhydrid, Z. Phys., 1934, 90, 728. [all data]

Lagerqvist, Lundh, et al., 1970
Lagerqvist, A.; Lundh, L.E.; Neuhaus, H., A grating order sorter for separation of high orders in a 5 m Fastie vacuum spectrograph, Phys. Scr., 1970, 1, 261. [all data]

Nilsson, 1948
Nilsson, Dissertation, Stockholm, 1948, 0. [all data]

Bengtsson-Knave, 1932
Bengtsson-Knave, E., Uber die bandenspektren einiger metallhydride, Nova Acta Regiae Soc. Sci. Ups., 1932, 8, 4, 1-98. [all data]

Grabe and Hulthen, 1939
Grabe, B.; Hulthen, E., Pradissoziationserscheinungen im spektrum des aluminiumhydrides, Z. Phys., 1939, 114, 470. [all data]

Bengtsson and Hulthen, 1929
Bengtsson, E.; Hulthen, E., Uber eine experimentelle prufung der kombinationsregeln unter der bandenspektren, Z. Phys., 1929, 52, 275. [all data]

Farkas, 1931
Farkas, L., Uber das absorptionsspektrum des aluminiumhydrids, Z. Phys., 1931, 70, 733. [all data]

Farkas and Levy, 1933
Farkas, L.; Levy, S., Messung der intensitatsverteilung und breite von pradissoziierenden linien des AlH-molekuls, Z. Phys., 1933, 84, 195. [all data]

Holst and Hulthen, 1934
Holst, W.; Hulthen, E., Eine untersuchung uber die bandenspektra des aluminiumhydrides und aluminiumdeutrides, Z. Phys., 1934, 90, 712. [all data]

Holst, 1934, 2
Holst, W., Uber ein neues ¹Σ*** → ¹Π-system des aluminiumhydrids, Z. Phys., 1934, 90, 735. [all data]

Olsson, 1938
Olsson, Dissertation, Stockholm, 1938, 0. [all data]

Kleman, Lagercrantz, et al., 1950
Kleman, B.; Lagercrantz, A.; Uhler, U., The presumed ¹Σ^--term in AlH, Ark. Fys., 1950, 2, 359. [all data]

Loginov, 1964
Loginov, V.A., The production of electronic band spectra by the exploding wire method, Opt. Spectrosc. Engl. Transl., 1964, 16, 220, In original 402. [all data]

Huron, 1969
Huron, B., Etude de la distribution d'intensite dans le spectre d'absorption du systeme X¹Σ-A¹Π de l'hydrure d'aluminium, Physica (Amsterdam), 1969, 41, 58. [all data]

Grimaldi, Lecourt, et al., 1966
Grimaldi, F.; Lecourt, A.; Lefebvre-Brion, H.; Moser, C.M., Calculation of Rydberg levels of BH and AlH, J. Mol. Spectrosc., 1966, 20, 341. [all data]

Herzberg and Mundie, 1940
Herzberg, G.; Mundie, L.G., On the predissociation of several diatomic molecules, J. Chem. Phys., 1940, 8, 263. [all data]

Hurley, 1961
Hurley, A.C., Electronic structure of the first row hydrides. III. Predissociation by rotation in the A¹Π state and the dissociation energy of BH, Proc. R. Soc. London A, 1961, 261, 237. [all data]

Klynning and Neuhaus, 1965
Klynning, L.; Neuhaus, H., Uber den Zeeman-Effeckt des AlH-Spektrums, Ark. Fys., 1965, 28, 249. [all data]

Zeeman and Ritter, 1954
Zeeman, P.B.; Ritter, G.J., New measurements on the A¹Π = X¹Σ band system of AlH, Can. J. Phys., 1954, 32, 555. [all data]

Meyer and Rosmus, 1975
Meyer, W.; Rosmus, P., PNO-Cl and CEPA studies of electron correlation effects. III. Spectroscopic constants and dipole moment functions for the ground states of the first-row and second-row diatomic hydrides, J. Chem. Phys., 1975, 63, 2356. [all data]

Cade and Huo, 1967
Cade, P.E.; Huo, W.M., Electronic structure of diatomic molecules. VII.A. Hartree-Fock wavefunctions and energy quantities for the ground states of the second-row hydrides, AH, J. Chem. Phys., 1967, 47, 649. [all data]

Cade, Bader, et al., 1969
Cade, P.E.; Bader, R.F.W.; Henneker, W.H.; Keaveny, I., Molecular charge distributions and chemical binding. IV. The second-row diatomic hydrides AH, J. Chem. Phys., 1969, 50, 5313. [all data]

Laws, Stevens, et al., 1971
Laws, E.A.; Stevens, R.M.; Lipscomb, W.N., Magnetic properties of A1H and N₂ from coupled Hartree-Fock theory, J. Chem. Phys., 1971, 54, 4269. [all data]

Notes

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• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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