Phosphinidene
- Formula: HP
- Molecular weight: 31.98170
- IUPAC Standard InChI: InChI=1S/HP/h1H
- IUPAC Standard InChIKey: BHEPBYXIRTUNPN-UHFFFAOYSA-N
- CAS Registry Number: 13967-14-1
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 253.55 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1967 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 196.35 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1967 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 1200. | 1200. to 6000. |
|---|---|---|
| A | 28.32196 | 28.54350 |
| B | -2.953172 | 6.165836 |
| C | 13.45662 | -0.924145 |
| D | -5.760950 | 0.055819 |
| E | 0.061045 | -0.614789 |
| F | 245.3351 | 243.2084 |
| G | 231.2974 | 227.0828 |
| H | 253.5504 | 253.5504 |
| Reference | Chase, 1998 | Chase, 1998 |
| Comment | Data last reviewed in June, 1967 | Data last reviewed in June, 1967 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(CAS Reg. No. 13937-34-3 • 4294967295) +
= CAS Reg. No. 13937-34-3
By formula: (CAS Reg. No. 13937-34-3 • 4294967295HP) + HP = CAS Reg. No. 13937-34-3
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 384. ± 34. | kJ/mol | N/A | Ervin and Lineberger, 2005 | gas phase; High level calcns( Curtiss, Raghavachari, et al., 1991, Ricca and Bauschlicher, 1998) give DH ca. 84 |
| ΔrH° | 354. ± 12. | kJ/mol | Ther | Bartmess, Scott, et al., 1979 | gas phase; The D-EA cycle does not close by 7 kcal/mol. The reason for this discrepancy is not known; value altered from reference due to change in acidity scale |
P- + =
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1538. ± 33. | kJ/mol | D-EA | Andersson, Lindahl, et al., 2007 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1515. ± 34. | kJ/mol | H-TS | Andersson, Lindahl, et al., 2007 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Ervin and Lineberger, 2005
Ervin, K.M.; Lineberger, W.C.,
Photoelectron spectroscopy of phosphorus hydride anions,
J. Chem. Phys., 2005, 122, 19, 194303, https://doi.org/10.1063/1.1881153
. [all data]
Curtiss, Raghavachari, et al., 1991
Curtiss, L.A.; Raghavachari, K.; Trucks, G.W.; Pople, J.A.,
Gaussian-2 Theory for Molecular Energies of First- and Second-row Compounds,
J. Chem. Phys., 1991, 94, 11, 7221, https://doi.org/10.1063/1.460205
. [all data]
Ricca and Bauschlicher, 1998
Ricca, A.; Bauschlicher, C.W., Jr.,
Accurate Heats of Formation for PHn, PHn+, and PHn-,
Chem. Phys. Lett., 1998, 285, 5-6, 455, https://doi.org/10.1016/S0009-2614(97)01468-1
. [all data]
Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr.,
The gas phase acidity scale from methanol to phenol,
J. Am. Chem. Soc., 1979, 101, 6047. [all data]
Andersson, Lindahl, et al., 2007
Andersson, P.; Lindahl, A.O.; Alfredsson, C.; Rogstrom, L.; Diehl, C.; Pegg, D.J.; Hanstorp, D.,
The electron affinity of phosphorus,
J. Phys. B - Atom. Mol. Opt. Phys., 2007, 40, 20, 4097-4107, https://doi.org/10.1088/0953-4075/40/20/010
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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