vanadium hydride
- Formula: HV
- Molecular weight: 51.9494
- CAS Registry Number: 13966-93-3
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
V- + = HV
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 339.7 ± 3.4 | kcal/mol | G+TS | Sallans, Lane, et al., 1985 | gas phase |
| ΔrH° | 340.9 ± 3.7 | kcal/mol | Acid | Feigerle, Corderman, et al., 1981 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 332.0 ± 3.0 | kcal/mol | IMRB | Sallans, Lane, et al., 1985 | gas phase |
| ΔrG° | 333.1 ± 5.2 | kcal/mol | H-TS | Feigerle, Corderman, et al., 1981 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S.,
Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH,
J. Am. Chem. Soc., 1985, 107, 4379. [all data]
Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C.,
Binding Energies and Structure of Transition Metal Negative Ions,
J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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