HSn
- Formula: HSn
- Molecular weight: 119.718
- CAS Registry Number: 13940-25-5
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
Sn- + = HSn
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1435. ± 13. | kJ/mol | D-EA | Vandevraye, Drag, et al., 2013 | gas phase; Given: 1.112070±0.000002 eV |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
View reactions leading to HSn+ (ion structure unspecified)
De-protonation reactions
Sn- + = HSn
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1435. ± 13. | kJ/mol | D-EA | Vandevraye, Drag, et al., 2013 | gas phase; Given: 1.112070±0.000002 eV |
Constants of diatomic molecules
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through August, 1977
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| A 2Δ | 1 | [4.904] 2 3 | [433E-6] 4 | [1.8546] | A ↔ X R | 23468.27 Z | ||||||
| ↳Watson and Simon, 1939; missing citation | ||||||||||||
| a 4Σ- | [5.3723] 5 | [298E-6] 6 | [1.7719] | a ↔ X 7 R | 15439.27 Z | |||||||
| ↳Watson and Simon, 1940; missing citation | ||||||||||||
| X 2Πr | 0 8 | [5.31488] 9 | [207.5E-6] | [1.78146] | ||||||||
Notes
| 1 | Spin coupling constants for v=0: A(v=0) = 20.41 Klynning, Lindgren, et al., 1965, AJ(v=0) = 0.0625 Klynning, Lindgren, et al., 1965, γ(v=0) = 1.23 Klynning, Lindgren, et al., 1965. For a more elaborate evaluation of these constants (including centrifugal distortion) see Kovacs and Vujisic, 1971. |
| 2 | Rotational constants of Klynning, Lindgren, et al., 1965 based on a modified Hill-Van Vleck expression; see also Kovacs and Vujisic, 1971. A case "c" treatment of the same data is given by Veseth, 1973. |
| 3 | Broadening of absorption lines above N' ~ 14 Klynning, Lindgren, et al., 1965, sharp cut-off in emission at N'=17 Watson and Simon, 1939. |
| 4 | H0 = -2.3E-7; see 2. |
| 5 | Spin splitting constants for v=0: λ(v=0) = 45.78 Klynning, Lindgren, et al., 1965, γ1(v=0) = 0.190 Klynning, Lindgren, et al., 1965, γ2(v=0) = 0.191 Klynning, Lindgren, et al., 1965. ΔB is the difference in B values between the states Ω = 1/2 and 3/2: ΔB = -0.0266 Klynning, Lindgren, et al., 1965. All constants derived by Klynning, Lindgren, et al., 1965 according to the modified expressions [see Klynning, Lindgren, et al., 1965 for the energy levels of a 4Σ state Hougen, 1962. For further refinements see Kovacs and Korwar, 1971, Kovacs and Pacher, 1971. The case "c" treatment of the same data by Veseth, 1973 gives B0 = 5.404, (Ω=1/2) Veseth, 1973 and B0 = 5.339, (Ω= 3/2) Veseth, 1973, respectively. For a discussion of 4Σ1/2- in terms of case "a'" coupling conditions see Kopp and Hougen, 1967. |
| 6 | H0 = -3.3E-8. |
| 7 | Rotational intensity distribution Klynning, 1966, Kopp and Hougen, 1967. |
| 8 | A0 = +2178.88 + 0.01719J(J+1) Klynning, Lindgren, et al., 1965; see, however, Kovacs and Vujisic, 1971. |
| 9 | Λ-type doubling Δ vfe(2Π1/2, v=0) = +1.003(J+1/2) - 1.76E-4(J+1/2)3 Klynning, Lindgren, et al., 1965. |
| 10 | From the predissociation in A 2Δ assuming dissociation into 3P2 + 2S. |
| 11 | Spin coupling constants for v=0: A(v=0)=8.52, AJ(v=0)= 0.0225, γ(v=0) = 0.555. The large difference from SnH remains unexplained; see Veseth, 1971, Veseth, 1973. |
| 12 | H0 = -0.135E-7; see 2. |
| 13 | Spin splitting constants for v=0: λ(v=0) = 45.0, γ1(v=0) = 0.076, γ2(v=0) = 0.0883. ΔB= -0.012 see 5. |
| 14 | H0 = -0.13E-8. |
| 15 | A0 = 2177.05 + 0.0080J(J+1). |
| 16 | Δ vfe(2Π1/2,v=0) = +0.5076(J+1/2) - 0.000045(J+1/2)3. |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Vandevraye, Drag, et al., 2013
Vandevraye, M.; Drag, C.; Blondel, C.,
Electron affinity of tin measured by photodetachment microscopy,
J. Phys. B: Atom. Mol. Opt. Phys., 2013, 46, 12, 125002, https://doi.org/10.1088/0953-4075/46/12/125002
. [all data]
Watson and Simon, 1939
Watson, W.W.; Simon, R.,
The spectrum of tin hydride at high pressure,
Phys. Rev., 1939, 55, 358. [all data]
Watson and Simon, 1940
Watson, W.W.; Simon, R.,
Spectra of lead hydride and tin hydride in the near infra-red,
Phys. Rev., 1940, 57, 708. [all data]
Klynning, Lindgren, et al., 1965
Klynning, L.; Lindgren, B.; Aslund, N.,
On the spectra of SnH and SnD,
Ark. Fys., 1965, 30, 141. [all data]
Kovacs and Vujisic, 1971
Kovacs, I.; Vujisic, B.,
Centrifugal distortion of the spin-orbit and spin-rotation interaction for doublet terms,
J. Phys. B:, 1971, 4, 1123. [all data]
Veseth, 1973
Veseth, L.,
Some anomalies in the electronic spectra of GeH, GeD, SnH, and SnD related to Hund's coupling case (c),
J. Mol. Spectrosc., 1973, 48, 283. [all data]
Hougen, 1962
Hougen, J.T.,
The rotational energy levels of diatomic molecules in 4Σ electronic states,
Can. J. Phys., 1962, 40, 598. [all data]
Kovacs and Korwar, 1971
Kovacs, I.; Korwar, V.M.,
General theory of the rotational structure of 4Σ states of diatomic molecules I,
J. Phys. B:, 1971, 4, 759. [all data]
Kovacs and Pacher, 1971
Kovacs, I.; Pacher, P.,
General theory of the rotational structure of 4Σ states of diatomic molecules: II,
J. Phys. B:, 1971, 4, 1633. [all data]
Kopp and Hougen, 1967
Kopp, I.; Hougen, J.T.,
Rotational energy levels of 1/2 states and intensities in 1/2-1/2 transitions: applications to some heavier hydrides,
Can. J. Phys., 1967, 45, 2581. [all data]
Klynning, 1966
Klynning, L.,
On the intensity distribution in the 4Σ-2Π band of SnH,
Ark. Fys., 1966, 31, 281. [all data]
Veseth, 1971
Veseth, L.,
Second-order spin-orbit splitting in 2Δ states of diatomic molecules,
Physica (Amsterdam), 1971, 56, 286. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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