Propazine
- Formula: C9H16ClN5
- Molecular weight: 229.710
- IUPAC Standard InChIKey: WJNRPILHGGKWCK-UHFFFAOYSA-N
- CAS Registry Number: 139-40-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 1,3,5-Triazine-2,4-diamine, 6-chloro-N,N'-bis(1-methylethyl)-; s-Triazine, 2-chloro-4,6-bis(isopropylamino)-; G 30028; Geigy 30,028; Gesamil; Milogard; Plantulin; Propasin; Propazin; Propazine (Herbicide); Primatol P; 2-Chlor-4,6-bis(isopropylamino)-s-triazine; 2-Chloro-4,6-bis(isopropylamino)-s-triazine; 2,4-Bis(isopropylamino)-6-chloro-s-triazine; 2,4-Bis(propylamino)-6-chlor-1,3,5-triazine; 6-Chloro-N,N'-bis(1-methylethyl)-1,3,5-triazine-2,4-diamine; 6-Chloro-N,N'-diisopropyl-1,3,5-triazine-2,4-diyldiamine; Milo-pro; Prozinex; 2,4-bis(1-methylethyl-amino)-6-chloro-s-triazine; 6-Chloro-N,N'-di(1-methylethyl)-[1,3,5]triazine-2,4-diamine; 1,3,5-Triazine-2,4-diamine, 6-chloro-N2,N4-bis(1-methylethyl)-; 2-Chloro-4,6-bis(isopropylamino)-1,3,5-triazine; NSC 26002; 6-Chloro-N,N'-(1-methylethyl)-[1,3,5]triazine-2,4-diamine
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | DB-1 | 190. | 1753.88 | Mijin, Antonovic, et al., 2003 | 30. m/0.256 mm/0.25 μm |
Capillary | DB-5 | 190. | 1763.13 | Mijin, Antonovic, et al., 2003 | 60. m/0.321 mm/0.25 μm |
Capillary | DB-1 | 190. | 1753.88 | Antonovic and Boncic-Caricic, 1994 | 30. m/0.256 mm/0.25 μm, N2 |
Capillary | DB-1 | 210. | 1767.32 | Antonovic and Boncic-Caricic, 1994 | 30. m/0.256 mm/0.25 μm, N2 |
Capillary | DB-1 | 230. | 1777.68 | Antonovic and Boncic-Caricic, 1994 | 30. m/0.256 mm/0.25 μm, N2 |
Capillary | DB-5 | 190. | 1763.13 | Antonovic and Boncic-Caricic, 1994 | 60. m/0.321 mm/0.25 μm, N2 |
Capillary | DB-5 | 210. | 1776.59 | Antonovic and Boncic-Caricic, 1994 | 60. m/0.321 mm/0.25 μm, N2 |
Capillary | OV-101 | 190. | 1733. | Valko and Lopata, 1982 | |
Capillary | OV-101 | 190. | 1733. | Matisová, Krupcík, et al., 1979 | N2; Column length: 69.7 m; Column diameter: 0.24 mm |
Kovats' RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-1 | 1735. | Hall, Whitehead, et al., 1986 | He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; Tstart: 100. C; Tend: 270. C |
Capillary | DB-5 | 1770. | Hall, Whitehead, et al., 1986 | He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; Tstart: 100. C; Tend: 270. C |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Carbowax 20M | 215. | 2633. | Leclercq and Pacáková, 1979 | N2, Chromosorb W |
Packed | Carbowax 20M | 190. | 2659. | Matisová, Krupcík, et al., 1979 | N2, Chromosorb W AW (80-100 mesh); Column length: 1.3 m |
Packed | Carbowax 20M | 215. | 2633. | Pacáková and Nemec, 1978 | N2, Chromosorb W; Column length: 1.4 m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SLB-5MS | 1756. | Mondello, Casilli, et al., 2007 | 30. m/0.25 mm/0.25 μm, He, 2. K/min; Tstart: 70. C; Tend: 300. C |
Capillary | SLB-5MS | 1761. | Mondello, Casilli, et al., 2007 | 30. m/0.25 mm/0.25 μm, He, 2. K/min; Tstart: 70. C; Tend: 300. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | 5 % Phenyl methyl siloxane | 1759. | Department of Food Safety and Welfare, 2006 | 30. m/0.25 mm/0.25 μm, Helium; Program: 50 0C(1 min) 25 0C/min -> 125 0C 10 0C/min -> 300 0C (10 min) |
Capillary | Ultra-1 | 1706. | Tameo and Kiyos, 1991 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mijin, Antonovic, et al., 2003
Mijin, D.Z.; Antonovic, D.; Jovanovic, B.Z.,
Gas chromatographic retention indices for N-substituted amino s-triazines on capillary columns. Part V. Temperature dependence of the retention index,
J. Serb. Chem. Soc., 2003, 68, 11, 825-831, https://doi.org/10.2298/JSC0311825M
. [all data]
Antonovic and Boncic-Caricic, 1994
Antonovic, D.G.; Boncic-Caricic, G.A.,
Gas chromatographic retention indices for N-substituted amino s-triazines on DB-1 and DB-5 capillary columns,
J. Serb. Chem. Soc., 1994, 59, 12, 993-996. [all data]
Valko and Lopata, 1982
Valko, K.; Lopata, A.,
Applicability of Gas-Liquid Chromatography in Determining Liquid-Liquid Partition Data,
J. Chromatogr., 1982, 252, 77-90, https://doi.org/10.1016/S0021-9673(01)88399-0
. [all data]
Matisová, Krupcík, et al., 1979
Matisová, E.; Krupcík, J.; Líska, O.; Szentiványi, N.,
Qualitative analysis of multi-component s-triazine herbicides by gas-liquid chromatography,
J. Chromatogr., 1979, 169, 261-269, https://doi.org/10.1016/0021-9673(75)85049-7
. [all data]
Hall, Whitehead, et al., 1986
Hall, G.L.; Whitehead, W.E.; Mourer, C.R.; Shibamoto, T.,
A new gas chromatographic retention index for pesticides and related compounds,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 5, 266-271, https://doi.org/10.1002/jhrc.1240090503
. [all data]
Leclercq and Pacáková, 1979
Leclercq, P.A.; Pacáková, V.,
Gas Chromatography and Mass Spectrometry of Bis(alkylamino)-s-triazines,
J. Chromatogr., 1979, 178, 1, 193-207, https://doi.org/10.1016/S0021-9673(00)89708-3
. [all data]
Pacáková and Nemec, 1978
Pacáková, V.; Nemec, I.,
Gas chromatographic, spectrophotometric and electrochemical behaviour of subsitituted s-triazines,
J. Chromatogr., 1978, 148, 1, 273-281, https://doi.org/10.1016/S0021-9673(00)99348-8
. [all data]
Mondello, Casilli, et al., 2007
Mondello, L.; Casilli, A.; Tranchida, P.Q.; Presti, M.L.; Dugo, P.; Dugo, G.,
Comprehensive gas chromatography coupled to mass spectrometry for the separation of pesticides in a very complex matrix,
Anal. Bioanal. Chem., 2007, 389, 6, 1755-1763, https://doi.org/10.1007/s00216-007-1412-y
. [all data]
Department of Food Safety and Welfare, 2006
Department of Food Safety, Ministry of Health; Welfare,
Analytical methods for residual compositional substances of agricultural chemicals, feed aadditives, and veterinary drugs in foods, 2006, retrieved from http://www.mhlw.go.jp/english/topics/foodsafety/positivelist060228/de/060526-1a.pdf. [all data]
Tameo and Kiyos, 1991
Tameo, O.; Kiyos, I.,
Simultaneous determination of pesticides by capillary gas chromatography,
Cannot be traslated (in Japan), 1991, 14, 2, 109-122. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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