Aluminate(1-), tetrafluoro-, sodium (1:1), (T-4)-
- Formula: AlF4Na
- Molecular weight: 125.9649207
- CAS Registry Number: 13821-15-3
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
AlF4- + AlF4Na = (AlF4- • AlF4Na)
By formula: AlF4- + AlF4Na = (AlF4- • AlF4Na)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 166. ± 9.2 | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 141. ± 13. | kJ/mol | TDAs | Sidorov, Nikitin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
F2O2P- + AlF4Na = (F2O2P- • AlF4Na)
By formula: F2O2P- + AlF4Na = (F2O2P- • AlF4Na)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 189. ± 21. | kJ/mol | N/A | Mavrin, Miletich, et al., 1989 | gas phase; ΔHf(A-) at 0 K; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D.,
Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-,
Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]
Mavrin, Miletich, et al., 1989
Mavrin, A.A.; Miletich, M.; Korobov, M.V.; Zmbov, K.; Sidorov, L.N.,
Mass-spectroscopic Thermodynamic Study of the Negative Ions of Phosphorous Oxide Fluorides,
Russ. J. Phys. Chem., 1989, 63, 500. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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