Rhenium, pentacarbonyliodo-
- Formula: C5IO5Re
- Molecular weight: 453.162
- IUPAC Standard InChI: InChI=1S/5CO.HI.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
- IUPAC Standard InChIKey: DGSSBNZHZQWZBU-UHFFFAOYSA-M
- CAS Registry Number: 13821-00-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Rhenium, pentacarbonyliodo-, (OC-6-22)-; Pentacarbonyliodorhenium
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
(cr) +
(cr) = 2
(cr)
By formula: C10O10Re2 (cr) + I2 (cr) = 2C5IO5Re (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -172. ± 18. | kJ/mol | PC | Harel and Adamson, 1986 | The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -157. ± 16. kJ/mol, and from the solution enthalpies of Re2(CO)10(cr), 34.3 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Re(CO)5(I)(cr), 34.7 ± 4.2 kJ/mol Harel and Adamson, 1986 |
(solution) +
(solution) = 2
(solution)
By formula: C10O10Re2 (solution) + I2 (solution) = 2C5IO5Re (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -157. ± 16. | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane; Please also see Adamson, Vogler, et al., 1978. |
C10MnO10Re (solution) + (solution) =
(solution) +
(solution)
By formula: C10MnO10Re (solution) + I2 (solution) = C5IO5Re (solution) + C5IMnO5 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -233. ± 13. | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harel and Adamson, 1986
Harel, Y.; Adamson, A.W.,
J. Phys. Chem., 1986, 90, 6693. [all data]
Adamson, Vogler, et al., 1978
Adamson, A.W.; Vogler, A.; Kunkely, H.; Wachter, R.,
J. Am. Chem. Soc., 1978, 100, 1298. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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