Lidocaine

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Gas Chromatography

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryBP-1200.1875.Japp, Gill, et al., 198725. m/0.22 mm/0.25 μm, N2
CapillaryBP-1200.1882.Japp, Gill, et al., 198725. m/0.53 mm/1. μm, N2
PackedSE-30180.1875.Musumarra, Scarlata, et al., 1987N2, 1% se-30 on Anachrom ABS(80-100mesh); Column length: 2. m
PackedSE-30220.1900.Mari, Bertol, et al., 1984Anakrom ABS; Column length: 2. m
PackedSE-30260.1850.Mari, Bertol, et al., 1984Anakrom ABS; Column length: 2. m
PackedOV-101170.1859.Delbeke, Debackere, et al., 1981 
PackedOV-101180.1866.Delbeke, Debackere, et al., 1981 
PackedOV-1200.1885.Berninger and Möller, 1977 

Kovats' RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
PackedOV-1011875.Maurer, 1990N2, Chromosorb G HP, 100. C @ 3. min, 30. K/min, 310. C @ 5. min; Column length: 0.60 m
CapillarySE-301869.Schepers, Wijsbeek, et al., 198225. m/0.49 mm/1.14 μm, 100. C @ 2. min, 8. K/min, 275. C @ 15. min

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
PackedOV-1011860.McLinden and Stenhouse, 1979N2, Chromosorb W; Column length: 2. m; Program: not specified

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySPB-11884.Christ, Noomano, et al., 198830. m/0.75 mm/1.0 μm, He, 10. K/min, 280. C @ 12. min; Tstart: 160. C
CapillaryCBP-11838.Oyama, Sano, et al., 1987N2, 6. K/min; Column length: 12. m; Column diameter: 0.53 mm; Tstart: 120. C; Tend: 250. C
PackedMethyl Silicone1881.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1890.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1880.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1880.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1882.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1882.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1882.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1882.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1890.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1892.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1895.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1865.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1882.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1890.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1890.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1890.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1893.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1895.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1875.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1875.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1875.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1875.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1875.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1880.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1880.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1880.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1880.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1880.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1885.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
PackedMethyl Silicone1895.Bogusz, Wijsbeek, et al., 1985120. C @ 4. min, 7. K/min, 290. C @ 10. min
CapillaryDB-11854.Perrigo, Peel, et al., 198515. m/0.32 mm/0.25 μm, He, 8. K/min, 280. C @ 5. min; Tstart: 120. C
CapillaryMethyl Silicone1852.0Newton and Foery, 198412. m/0.2 mm/0.33 μm, He, 50. C @ 1. min, 20. K/min, 300. C @ 3. min
CapillaryDB-11854.Perrigo, Ballantyne, et al., 198415. m/0.25 mm/0.25 μm, He, 8. K/min, 280. C @ 5. min; Tstart: 120. C
CapillaryDB-11860.Perrigo, Ballantyne, et al., 198415. m/0.25 mm/0.25 μm, He, 12. K/min, 280. C @ 5. min; Tstart: 120. C
CapillaryDB-11863.Perrigo, Ballantyne, et al., 198415. m/0.25 mm/0.25 μm, He, 15. K/min, 280. C @ 5. min; Tstart: 120. C
CapillaryDB-11848.Perrigo, Ballantyne, et al., 198415. m/0.25 mm/0.25 μm, He, 5. K/min, 280. C @ 5. min; Tstart: 120. C
CapillarySE-301842.Anderson and Stafford, 198315. m/0.25 mm/0.25 μm, He, 5. K/min; Tstart: 100. C; Tend: 295. C
PackedSE-301865.Perrigo and Peel, 1981N2, Chromosorb W, 130. C @ 2. min, 8. K/min, 290. C @ 8. min; Column length: 1.8 m

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryCP Sil 5 CB1881.Aderjan and Bogusz, 198810. m/0.53 mm/5.0 μm, He; Program: 100 0C (2 min ) 15 0C/min -> 200 0C 10 0C/min -> 300 0C (8 min hold)
CapillaryCP Sil 5 CB1870.Aderjan and Bogusz, 198810. m/0.53 mm/5.0 μm, He; Program: not specified
CapillaryBP-11857.Stowell and Wilson, 198712. m/0.22 mm/0.25 μm, He; Program: 120C => 8C/min => 270C => 25C/min => 300C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPolymethylsiloxane, (PMS-20000)1870.Gambaro, Saligari, et al., 199712. m/0.20 mm/0.33 μm, He, 10. K/min; Tstart: 160. C; Tend: 300. C
CapillaryDB-51842.Phillips, Logan, et al., 199015. m/0.25 mm/0.2 μm, He, 10. K/min; Tstart: 185. C; Tend: 270. C
CapillaryDB-11844.Anderson and Fuller, 198710. m/0.53 mm/2.65 μm, He, 5. K/min; Tstart: 130. C; Tend: 230. C
CapillaryBP-11842.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He, 5. K/min; Tstart: 100. C; Tend: 295. C
CapillaryBP-11854.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He, 8. K/min; Tstart: 120. C; Tend: 280. C
CapillaryBP-11852.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He, 20. K/min; Tstart: 50. C; Tend: 300. C
PackedSE-301860.Marozzi, Gambaro, et al., 1982Gas Chrom P, 2.5 K/min; Column length: 2. m; Tstart: 120. C; Tend: 200. C
PackedSE-301865.Peel and Perrigo, 1976Nitrogen, Chromosorb W AW DMS (80-100 mesh), 130. C @ 2. min, 8. K/min, 290. C @ 8. min; Column length: 2. m
PackedSE-301865.Peel and Perrigo, 1975N2, Chromosorb W AW DMS, 130. C @ 2. min, 8. K/min, 290. C @ 8. min; Column length: 2. m

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
Capillary5 % Phenyl methyl siloxane1924.Grigoriev and Savchuk, 201025. m/0.20 mm/0.33 μm; Program: 50 0C (0.5 min) 99 0C/min -> 100 0C (1 min) 15 0C/min -> 280 0C (20 min)
Capillary5 % Phenyl methyl siloxane1924.Grigoriev and Savchuk, 201025. m/0.20 mm/0.33 μm; Program: 50 0C (0.5 min) 99 0C/min -> 100 0C (1 min) 15 0C/min -> 280 0C (20 min)
CapillaryHP-11875.Grigor'ev, Bozhko, et al., 2009Helium; Program: not specified
CapillaryPolymethylsiloxane, (PMS-20000)1841.Gambaro, Saligari, et al., 199712. m/0.20 mm/0.33 μm, He; Program: not specified
CapillaryPolymethylsiloxane, (PMS-20000)1842.Gambaro, Saligari, et al., 199712. m/0.20 mm/0.33 μm, He; Program: not specified
CapillaryBP-11856.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He; Program: 120 0X 8 0C/min -> 270 0C 25 0C/min -> 300 0C (5 min)
CapillaryBP-11857.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He; Program: 120 0X 8 0C/min -> 270 0C 25 0C/min -> 300 0C (5 min)
CapillaryBP-11857.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He; Program: 120 0X 8 0C/min -> 270 0C 25 0C/min -> 300 0C (5 min)
CapillaryBP-11858.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He; Program: 120 0X 8 0C/min -> 270 0C 25 0C/min -> 300 0C (5 min)
CapillaryBP-11858.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He; Program: 120 0X 8 0C/min -> 270 0C 25 0C/min -> 300 0C (5 min)
CapillaryBP-11860.Stowell and Wilson, 198512. m/0.22 mm/0.25 μm, He; Program: not specified
OtherMethyl Silicone1870.Ardrey and Moffat, 1981Program: not specified

References

Go To: Top, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Japp, Gill, et al., 1987
Japp, M.; Gill, R.; Osselton, M.D., Comparison of drug retention indices determined on packed, wide bore capillary and narrow bore capillary columns, J. Forensic Sci., 1987, 32, 6, 1574-1586. [all data]

Musumarra, Scarlata, et al., 1987
Musumarra, G.; Scarlata, G.; Romano, G.; Cappello, G.; Clementi, S.; Giulietti, G., Qualitative organic analysis. Part 2. Identification of drugs by principal components analysis of standardized TLC data in four eluent systems and of retention indices on SE 30, J. Anal. Toxicol., 1987, 11, 4, 154-163, https://doi.org/10.1093/jat/11.4.154 . [all data]

Mari, Bertol, et al., 1984
Mari, F.; Bertol, E.; Tosti, M., Benzoyltropeine, an unusual substance in street heroin samples, Bull. Narc., 1984, 1, 59-67. [all data]

Delbeke, Debackere, et al., 1981
Delbeke, F.T.; Debackere, M.; Desmet, N., Detection of some local anaesthetics in horse urine and plasma by gas-liquid chromatography, J. Chromatogr., 1981, 206, 3, 594-599, https://doi.org/10.1016/S0021-9673(00)88931-1 . [all data]

Berninger and Möller, 1977
Berninger, H.; Möller, M.R., Retentionsindices zur gaschromatographischen Identifizierung von Arzneimitteln, Arch. Toxicol., 1977, 37, 4, 295-305, https://doi.org/10.1007/BF00330821 . [all data]

Maurer, 1990
Maurer, H.H., Identification of antiarrhythmic drugs and their metabolites in urine, Arch. Toxicol., 1990, 64, 3, 218-230, https://doi.org/10.1007/BF02010728 . [all data]

Schepers, Wijsbeek, et al., 1982
Schepers, P.; Wijsbeek, J.; Franke, J.P.; de Zeeuw, R.A., Applicability of capillary gas chromatography to substance identification in toxicology by means of retention indices, J. Forensic Sci., 1982, 27, 1, 49-60. [all data]

McLinden and Stenhouse, 1979
McLinden, V.J.; Stenhouse, A.M., A chromatography system for drug identification, Forensic Sci. Int., 1979, 13, 71-79, https://doi.org/10.1016/0379-0738(79)90265-2 . [all data]

Christ, Noomano, et al., 1988
Christ, D.W.; Noomano, P.; Rosas, M.; Rhone, D., Retention indices by wide-bore capillary gas chromatography with nitrogen-phosphorus detection, J. Anal. Toxicol., 1988, 12, 2, 84-88, https://doi.org/10.1093/jat/12.2.84 . [all data]

Oyama, Sano, et al., 1987
Oyama, N.; Sano, T.; Syoyama, M.; Maeda, K., Studies on systematic analysis of poisonous compounds in forensic chemistry. II. Application of capillary column gas chromatography to substance identification by means of retention indices, Eisei Kagaku, 1987, 33, 5, 342-348, https://doi.org/10.1248/jhs1956.33.342 . [all data]

Bogusz, Wijsbeek, et al., 1985
Bogusz, M.; Wijsbeek, J.; Franke, J.P.; de Zeeuw, R.A.; Gierz, J., Impact of biological matrix, drug concentration, and method of isolation on detectability and variability of retention index values in gas chromatography, J. Anal. Toxicol., 1985, 9, 2, 49-54, https://doi.org/10.1093/jat/9.2.49 . [all data]

Perrigo, Peel, et al., 1985
Perrigo, B.J.; Peel, H.W.; Ballantyne, D.J., Use of Dual-Column Fused-Silica Capillary Gas Chromatography in Combination with Detector Response Factors for Analytical Toxicology., J. Chromatogr., 1985, 341, 81-88, https://doi.org/10.1016/S0378-4347(00)84011-6 . [all data]

Newton and Foery, 1984
Newton, B.; Foery, R.F., Retention indices and dual capillary gas chromatography for rapid identification of sedative hypnotic drugs in emergency toxicology, J. Anal. Toxicol., 1984, 8, 3, 129-134, https://doi.org/10.1093/jat/8.3.129 . [all data]

Perrigo, Ballantyne, et al., 1984
Perrigo, B.J.; Ballantyne, D.J.; Peel, H.W., Condierations in developing a data base for drugs on a DBI capillary column, J. Can. Soc. Forensic Sci., 1984, 17, 2, 41-49, https://doi.org/10.1080/00085030.1984.10757360 . [all data]

Anderson and Stafford, 1983
Anderson, W.H.; Stafford, D.T., Applications of capillary gas chromatography in routine toxicological analyses, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 5, 247-254, https://doi.org/10.1002/jhrc.1240060506 . [all data]

Perrigo and Peel, 1981
Perrigo, B.J.; Peel, H.W., The use of retention indices and temperature-programmed gas chromatography in analytical toxicology, J. Chromatogr. Sci., 1981, 19, 5, 219-226, https://doi.org/10.1093/chromsci/19.5.219 . [all data]

Aderjan and Bogusz, 1988
Aderjan, R.; Bogusz, M., Nitroalkanes as a multidetector retention index scale for drug identification in gas chromatography, J. Chromatogr., 1988, 454, 345-351, https://doi.org/10.1016/S0021-9673(00)88629-X . [all data]

Stowell and Wilson, 1987
Stowell, A.; Wilson, L.W., A simple approach to the interlaboratory transfer of drug retention indices determined by temperature programmed capillary gas chromatography, J. Forensic Sci., 1987, 32, 5, 1214-1220. [all data]

Gambaro, Saligari, et al., 1997
Gambaro, V.; Saligari, E.; Froldi, R.; Bianchi, L., Analysis of street drugs by means of HRGC, Bollettino Chimico Farmaceutica, 1997, 36, 4, 359-367. [all data]

Phillips, Logan, et al., 1990
Phillips, A.M.; Logan, B.K.; Stafford, D.T., Further applications for capillary gas chromatography in routine quantitative toxicological analyses, J. Hi. Res. Chromatogr., 1990, 13, 11, 754-758, https://doi.org/10.1002/jhrc.1240131106 . [all data]

Anderson and Fuller, 1987
Anderson, W.H.; Fuller, D.C., A simplified procedure for the isolation, characterization, and identification of weak acid and neutral drugs from whole blood, J. Anal. Toxicol., 1987, 11, 5, 198-204, https://doi.org/10.1093/jat/11.5.198 . [all data]

Stowell and Wilson, 1985
Stowell, A.; Wilson, L., Use of retention indices in drug screening by capillary gas chromatography, Rep. # CD 2362, Department of Scientific and Industrial Reseach, Chemistry Division, Lower Hutt, NZ, 1985, 32. [all data]

Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F., Use of the retention index in gas chromatographic studies of drugs, J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185 . [all data]

Peel and Perrigo, 1976
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can. Soc. Forens. Sci. J., 1976, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]

Peel and Perrigo, 1975
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can.Soc.Forens.Sci.J., 1975, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]

Grigoriev and Savchuk, 2010
Grigoriev, A.M.; Savchuk, S.A., Correlation of the parameters of screening libraries of the gas-chromatographic retention data, Rus. J. Anal. Chem. (Engl. Transl.), 2010, 65, 4, 388-397. [all data]

Grigor'ev, Bozhko, et al., 2009
Grigor'ev, A.M.; Bozhko, E.S.; Rudakova, L.V., Use of correlation between retention indices on low-polarity phases for screening comp-lex mixtures by gas chromatography-mass spectrometry, Rus. J. Anal. Chem., 2009, 64, 2, 140-143, https://doi.org/10.1134/S1061934809020087 . [all data]

Ardrey and Moffat, 1981
Ardrey, R.E.; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. Chromatogr., 1981, 220, 3, 195-252, https://doi.org/10.1016/S0021-9673(00)81925-1 . [all data]


Notes

Go To: Top, Gas Chromatography, References