Manganese, pentacarbonylmethyl-
- Formula: C6H3MnO5
- Molecular weight: 210.0231
- IUPAC Standard InChI: InChI=1S/5CO.CH3.Mn/c5*1-2;;/h;;;;;1H3;
- IUPAC Standard InChIKey: KJJLHDHVFFAISC-UHFFFAOYSA-N
- CAS Registry Number: 13601-24-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Manganese, pentacarbonylmethyl-, (OC-6-21)-; Methyl pentacarbonylmanganese; Methylmanganese pentacarbonyl; Pentacarbonylmethylmanganese; CH3(CO)5Mn
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -181. ± 1. | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | -179.5 ± 0.98 | kcal/mol | Review | Martinho Simões | Selected data |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 14.4 ± 0.41 | kcal/mol | HAL-HFC | Hieber and Braun, 1958 | MS |
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 14.4 | 293. to 403. | Hieber and Wagner, 1958 | AC |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Hieber and Braun, 1958
Hieber, W.; Braun, G.,
Justus Liebigs Ann. Chem., 1958, 24, 618. [all data]
Hieber and Wagner, 1958
Hieber, Walter; Wagner, Gerhard,
Über Organomanganpentacarbonyle, I,
Justus Liebigs Ann. Chem., 1958, 618, 1, 24-30, https://doi.org/10.1002/jlac.19586180104
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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