H5NSi
- Formula: H5NSi
- Molecular weight: 47.1319
- CAS Registry Number: 13598-78-2
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
H4NSi- + = H5NSi
By formula: H4NSi- + H+ = H5NSi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1571. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1540. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
De-protonation reactions
H4NSi- + = H5NSi
By formula: H4NSi- + H+ = H5NSi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1571. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1540. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Krempp and Damrauer, 1995
Krempp, M.; Damrauer, R.,
The Gas-phase Chemistry of Silamide Ions,
Organomet., 1995, 14, 1, 170, https://doi.org/10.1021/om00001a027
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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