Copper monohydride
- Formula: CuH
- Molecular weight: 64.554
- IUPAC Standard InChI: InChI=1S/Cu.H
- IUPAC Standard InChIKey: JJFLDSOAQUJVBF-UHFFFAOYSA-N
- CAS Registry Number: 13517-00-5
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
Cu- + =
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 346.8 ± 2.6 | kcal/mol | D-EA | Bilodeau, Scheer, et al., 1998 | gas phase |
| ΔrH° | 346.8 ± 2.6 | kcal/mol | D-EA | Leopold, Ho, et al., 1987 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.4440 ± 0.0060 | LPES | Calvi, Andrews, et al., 2007 |
De-protonation reactions
Cu- + =
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 346.8 ± 2.6 | kcal/mol | D-EA | Bilodeau, Scheer, et al., 1998 | gas phase |
| ΔrH° | 346.8 ± 2.6 | kcal/mol | D-EA | Leopold, Ho, et al., 1987 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bilodeau, Scheer, et al., 1998
Bilodeau, R.C.; Scheer, M.; Haugen, H.K.,
Infrared Laser Photodetachment of Transition Metal Negative Ions: Studies on Cr-, Mo-, Cu-, and Ag-,
J. Phys. B: Atom. Mol. Opt. Phys., 1998, 31, 17, 3885-3891, https://doi.org/10.1088/0953-4075/31/17/013
. [all data]
Leopold, Ho, et al., 1987
Leopold, D.G.; Ho, J.; Lineberger, W.C.,
Photoelectron Spectroscopy of Mass-selected Metal Cluster Anions. I. Cun-, n=1-10,
J. Chem. Phys., 1987, 86, 4, 1715, https://doi.org/10.1063/1.452170
. [all data]
Calvi, Andrews, et al., 2007
Calvi, R.M.D.; Andrews, D.H.; Lineberger, W.C.,
Negative ion photoelectron spectroscopy of copper hydrides,
Chem. Phys. Lett., 2007, 442, 1-3, 12-16, https://doi.org/10.1016/j.cplett.2007.05.060
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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