Aluminum chloride fluoride


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-189.00kcal/molReviewChase, 1998Data last reviewed in June, 1976
Quantity Value Units Method Reference Comment
gas,1 bar74.405cal/mol*KReviewChase, 1998Data last reviewed in June, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 6000.
A 19.16890
B 0.591596
C -0.159033
D 0.013504
E -0.265743
F -195.6310
G 95.93760
H -189.0000
ReferenceChase, 1998
Comment Data last reviewed in June, 1976

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion • Aluminum chloride fluoride)

By formula: Cl- + AlCl2F = (Cl- • AlCl2F)

Quantity Value Units Method Reference Comment
Δr75.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiemnts at 800-1100K. See also AlCl3..F-; value altered from reference due to conversion from electron convention to ion convention

Fluorine anion + Aluminum chloride fluoride = (Fluorine anion • Aluminum chloride fluoride)

By formula: F- + AlCl2F = (F- • AlCl2F)

Quantity Value Units Method Reference Comment
Δr119.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion • Aluminum chloride fluoride)

By formula: Cl- + AlCl2F = (Cl- • AlCl2F)

Quantity Value Units Method Reference Comment
Δr75.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiemnts at 800-1100K. See also AlCl3..F-; value altered from reference due to conversion from electron convention to ion convention

Fluorine anion + Aluminum chloride fluoride = (Fluorine anion • Aluminum chloride fluoride)

By formula: F- + AlCl2F = (F- • AlCl2F)

Quantity Value Units Method Reference Comment
Δr119.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Pervova, Korobov, et al., 1992
Pervova, Y.U.; Korobov, M.V.; Sidorov, L.N., Enthalpies of Bonds Rupture in AlClnF4-n(-) Anions, Russ. J. Phys. Chem., 1992, 66, 635. [all data]


Notes

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