Copper, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-

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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

ΔsubH° (kJ/mol) Method Reference Comment
127.0 ± 1.2N/ARibeiro da Silva, 1995AC
127.1 ± 1.2N/ARibeiro da Silva, 1995AC
127.0 ± 1.1N/ARibeiro da Silva, 1995AC
116.6 ± 2.0CRibeiro da Silva and Ferrão, 1994AC
115.1 ± 2.1N/AMalkerova, Alikhanyan, et al., 1991Based on data from 315. to 386. K.; AC
127.5 ± 3.2N/AMurata, Sakiyama, et al., 1985AC
154. ± 22.N/ABurkinshaw and Mortimer, 1984AC
109.9 ± 3.4CRibeiro Da Silva, Ribeiro Da Silva, et al., 1984AC

References

Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, 1995
Ribeiro da Silva, M., Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) β-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014 . [all data]

Ribeiro da Silva and Ferrão, 1994
Ribeiro da Silva, Manuel A.V.; Ferrão, M. Luisa C.C.H., Enthalpy of sublimation of bis(pentane-2,4-dionato)copper(II), The Journal of Chemical Thermodynamics, 1994, 26, 3, 315-317, https://doi.org/10.1016/0021-9614(94)90008-6 . [all data]

Malkerova, Alikhanyan, et al., 1991
Malkerova, I.P.; Alikhanyan, A.S.; Filatov, I.Yu.; Kazanskaya, I.L.; Sevast'yanov, V.G., Volatility and structure of copper(II), palladium(II) and rhodium(II) acetylacetonates and copper(II) propionylacetonate, Zh. Neorg. Khim., 1991, 36, 12, 3112. [all data]

Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S., Sublimation calorimetric studies using a calvet microcalorimeter, Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8 . [all data]

Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T., Enthalpies of sublimation of transition metal complexes, J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075 . [all data]

Ribeiro Da Silva, Ribeiro Da Silva, et al., 1984
Ribeiro Da Silva, Manuel A.V.; Ribeiro Da Silva, Maria D.M.C.; Carvalho, Ana P.S.M.C.; Akello, Margaret J.; Pilcher, Geofrey, Standard enthalpies of formation of bis(pentane-2,4-dionato)Cu(II) and of four bis(methyl-substituted heptane-3,5-dionato)Cu(II) complexes: the mean (Cu«58872»O) bond-dissociation enthalpies, The Journal of Chemical Thermodynamics, 1984, 16, 2, 137-144, https://doi.org/10.1016/0021-9614(84)90146-0 . [all data]


Notes

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