Copper, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-
- Formula: C10H14CuO4
- Molecular weight: 261.762
- IUPAC Standard InChIKey: QYJPSWYYEKYVEJ-FDGPNNRMSA-L
- CAS Registry Number: 13395-16-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: Bis(acetylacetonato)copper; Copper, bis(2,4-pentanedionato)-; Bis(2,4-pentanedionato)copper; Copper acetylacetonate; Copper bis(acetylacetonate); Copper diacetylacetonate; Copper(II) acetylacetonate; Cupric acetylacetonate; CD 9; Copper(II) 2,4-pentanedionate; Copper bis(2,4-pentanedionate); Copper, bis(2,4-pentanedionato-O,O')-; CD 9Thimet G; copper(II) 4-oxopent-2-en-2-olate
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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
ΔsubH° (kJ/mol) | Method | Reference | Comment |
---|---|---|---|
127.0 ± 1.2 | N/A | Ribeiro da Silva, 1995 | AC |
127.1 ± 1.2 | N/A | Ribeiro da Silva, 1995 | AC |
127.0 ± 1.1 | N/A | Ribeiro da Silva, 1995 | AC |
116.6 ± 2.0 | C | Ribeiro da Silva and Ferrão, 1994 | AC |
115.1 ± 2.1 | N/A | Malkerova, Alikhanyan, et al., 1991 | Based on data from 315. to 386. K.; AC |
127.5 ± 3.2 | N/A | Murata, Sakiyama, et al., 1985 | AC |
154. ± 22. | N/A | Burkinshaw and Mortimer, 1984 | AC |
109.9 ± 3.4 | C | Ribeiro Da Silva, Ribeiro Da Silva, et al., 1984 | AC |
References
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ribeiro da Silva, 1995
Ribeiro da Silva, M.,
Vapour pressures and standard molar enthalpies of sublimation of seven crystalline copper(II) β-diketonates. The mean molar (Cu-O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1995, 27, 2, 175-190, https://doi.org/10.1006/jcht.1995.0014
. [all data]
Ribeiro da Silva and Ferrão, 1994
Ribeiro da Silva, Manuel A.V.; Ferrão, M. Luisa C.C.H.,
Enthalpy of sublimation of bis(pentane-2,4-dionato)copper(II),
The Journal of Chemical Thermodynamics, 1994, 26, 3, 315-317, https://doi.org/10.1016/0021-9614(94)90008-6
. [all data]
Malkerova, Alikhanyan, et al., 1991
Malkerova, I.P.; Alikhanyan, A.S.; Filatov, I.Yu.; Kazanskaya, I.L.; Sevast'yanov, V.G.,
Volatility and structure of copper(II), palladium(II) and rhodium(II) acetylacetonates and copper(II) propionylacetonate,
Zh. Neorg. Khim., 1991, 36, 12, 3112. [all data]
Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S.,
Sublimation calorimetric studies using a calvet microcalorimeter,
Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8
. [all data]
Burkinshaw and Mortimer, 1984
Burkinshaw, Philip M.; Mortimer, Colin T.,
Enthalpies of sublimation of transition metal complexes,
J. Chem. Soc., Dalton Trans., 1984, 1, 75, https://doi.org/10.1039/dt9840000075
. [all data]
Ribeiro Da Silva, Ribeiro Da Silva, et al., 1984
Ribeiro Da Silva, Manuel A.V.; Ribeiro Da Silva, Maria D.M.C.; Carvalho, Ana P.S.M.C.; Akello, Margaret J.; Pilcher, Geofrey,
Standard enthalpies of formation of bis(pentane-2,4-dionato)Cu(II) and of four bis(methyl-substituted heptane-3,5-dionato)Cu(II) complexes: the mean (Cu«58872»O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1984, 16, 2, 137-144, https://doi.org/10.1016/0021-9614(84)90146-0
. [all data]
Notes
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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