Reaction data

Hydrogen + 1-Hexene = n-Hexane


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

ΔrH° (kJ/mol) Method Reference Comment
-126.7 ± 0.52ChydRogers, Crooks, et al., 1987liquid phase; ALS
-126. ± 1.ChydMolnar, Rachford, et al., 1984liquid phase; solvent: Dioxane; ALS
-123.3 ± 1.2ChydMolnar, Rachford, et al., 1984liquid phase; solvent: Hexane; ALS
-123.3 ± 0.79ChydRogers, Papadimetriou, et al., 1975liquid phase; solvent: Hexane; ALS
-126.6 ± 1.0ChydRogers and Skanupong, 1974liquid phase; solvent: Hexane; See Rogers and Skanupong, 1979; ALS
-125.1 ± 1.3ChydBretschneider and Rogers, 1970liquid phase; solvent: glacial acetic acid; ALS
-126.6 ± 0.8ChydSkinner and Snelson, 1959liquid phase; solvent: Acetic acid; ALS
-126. ± 2.ChydFlitcroft, Skinner, et al., 1957gas phase; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rogers, Crooks, et al., 1987
Rogers, D.W.; Crooks, E.; Dejroongruang, K., Enthalpies of hydrogenation of the hexenes, J. Chem. Thermodyn., 1987, 19, 1209-1215. [all data]

Molnar, Rachford, et al., 1984
Molnar, A.; Rachford, R.; Smith, G.V.; Liu, R., Heats of hydrogenation by a simple and rapid flow calorimetric method, Appl. Catal., 1984, 9, 219-223. [all data]

Rogers, Papadimetriou, et al., 1975
Rogers, D.W.; Papadimetriou, P.M.; Siddiqui, N.A., An improved hydrogen microcalorimeter for use with large molecules, Mikrochim. Acta, 1975, 2, 389-400. [all data]

Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect, J. Phys. Chem., 1974, 78, 2569-2572. [all data]

Rogers and Skanupong, 1979
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect (additions and corrections), J. Phys. Chem., 1979, 83, 2430. [all data]

Bretschneider and Rogers, 1970
Bretschneider, E.; Rogers, D.W., A new microcalorimeter: heats of hydrogenation of four monoolefins, Mikrochim. Acta, 1970, 482-490. [all data]

Skinner and Snelson, 1959
Skinner, H.A.; Snelson, A., Heats of hydrogenation Part 3., Trans. Faraday Soc., 1959, 55, 405-407. [all data]

Flitcroft, Skinner, et al., 1957
Flitcroft, T.; Skinner, H.A.; Whiting, M.C., Heats of hydrogenation Part 1.-Dodeca-3:9 and -5:7 Diynes, Trans. Faraday Soc., 1957, 53, 784-790. [all data]


Notes

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