Borane-methyl sulfide complex

• Formula: C₂H₆S·BH₃
• Molecular weight: 75.969
• IUPAC Standard InChI: InChI=1S/C2H9BS/c1-4(2)3/h1-3H3 Copy

  
• IUPAC Standard InChIKey: IRTZFNXVGJHNHS-UHFFFAOYSA-N Copy
• CAS Registry Number: 13292-87-0
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Borane-dimethylsulfide; Borane dimethylsulfide complex; Dimethyl sulfide borane; Boron, trihydro[thiobis[methane]]-, (T-4)-; Methyl sulfide, compd. with borane (1:1); Borane, compd. with dimethylsulfide; dimethyl sulphide--borane; Dimethyl sulfide-borane complex
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• Information on this page:
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₂H₈BS^- +  =

By formula: C₂H₈BS^- + H⁺ = (C₂H₆S).(BH₃)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C₂H₈BS^- +  =

By formula: C₂H₈BS^- + H⁺ = (C₂H₆S).(BH₃)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Ren, Workman, et al., 1998
Ren, J.H.; Workman, D.B.; Squires, R.R., Gas-phase negative ion chemistry of Lewis acid-base complexes, J. Am. Chem. Soc., 1998, 120, 40, 10511-10522, https://doi.org/10.1021/ja9804518 . [all data]

Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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