CH4AlFO


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH3AlFO- + Hydrogen cation = CH4AlFO

By formula: CH3AlFO- + H+ = CH4AlFO

Quantity Value Units Method Reference Comment
Δr350.8 ± 4.1kcal/molG+TSDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc
Quantity Value Units Method Reference Comment
Δr344.0 ± 4.0kcal/molIMRBDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

CH3AlFO- + Hydrogen cation = CH4AlFO

By formula: CH3AlFO- + H+ = CH4AlFO

Quantity Value Units Method Reference Comment
Δr350.8 ± 4.1kcal/molG+TSDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc
Quantity Value Units Method Reference Comment
Δr344.0 ± 4.0kcal/molIMRBDamrauer, Krempp, et al., 1991gas phase; Between tBuSH, HOAc

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Krempp, et al., 1991
Damrauer, R.; Krempp, M.; Schmidt, M.W.; Gordon, M.S., Gas-Phase Chemistry of the Dimethylaluminum Oxide Ion and Related Aluminum Oxide Ions - Comparison of Reactivity with Siloxide Ions, J. Am. Chem. Soc., 1991, 113, 7, 2393, https://doi.org/10.1021/ja00007a007 . [all data]


Notes

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