nickel monoxide
- Formula: NiO
- Molecular weight: 74.6928
- CAS Registry Number: 1313-99-1
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Constants of diatomic molecules
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through April, 1975
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Three additional systems in the same spectral region. | ||||||||||||
| ↳Rosen, 1945; Malet and Rosen, 1945 | ||||||||||||
| b | (a + 21262) | (570) H | b → a R | (21135) H | ||||||||
| ↳Rosen, 1945; Malet and Rosen, 1945 | ||||||||||||
| a | a | (825) H | ||||||||||
| B | (16447) | (560) H | B → X R | (16420) H | ||||||||
| ↳Rosen, 1945; Malet and Rosen, 1945 | ||||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| A | (12725) | (475) H | A → X R | (12655) H | ||||||||
| ↳Rosen, 1945; Malet and Rosen, 1945 | ||||||||||||
| (X) | 0 | (615) H | ||||||||||
Notes
| 1 | Thermochemical value (mass spectrometry.) Grimley, Burns, et al., 1961, recalculated Smoes, Mandy, et al., 1972. See also Brewer and Mastick, 1951, Huldt and Lagerqvist, 1954. |
References
Go To: Top, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rosen, 1945
Rosen, B.,
Spectra of diatomic oxides by the method of exploded wire,
Nature (London), 1945, 156, 570. [all data]
Malet and Rosen, 1945
Malet, L.; Rosen, B.,
Etude spectroscopique des molecules NiO et CoO,
Bull. Soc. R. Sci. Liege, 1945, 14, 382. [all data]
Grimley, Burns, et al., 1961
Grimley, R.T.; Burns, R.P.; Inghram, M.G.,
Thermodynamics of the vaporization of nickel oxide,
J. Chem. Phys., 1961, 35, 551. [all data]
Smoes, Mandy, et al., 1972
Smoes, S.; Mandy, F.; Vander Auwera-Mahieu, A.; Drowart, J.,
Determination by the mass spectrometric Knudsen cell method of the dissociation energies of the group IB chalcogenides,
Bull. Soc. Chim. Belg., 1972, 81, 45. [all data]
Brewer and Mastick, 1951
Brewer, L.; Mastick, D.F.,
The stability of gaseous diatomic oxides,
J. Chem. Phys., 1951, 19, 834. [all data]
Huldt and Lagerqvist, 1954
Huldt, L.; Lagerqvist, A.,
Uber die Dissoziationsenergie des gasformigen Nickeloxydes NiO,
Z. Naturforsch. A, 1954, 9, 358. [all data]
Notes
Go To: Top, Constants of diatomic molecules, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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