Sodium hydroxide

• Formula: HNaO
• Molecular weight: 39.9971
• IUPAC Standard InChI: InChI=1S/Na.H2O/h;1H2/q+1;/p-1 Copy

  
• IUPAC Standard InChIKey: HEMHJVSKTPXQMS-UHFFFAOYSA-M Copy
• CAS Registry Number: 1310-73-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • Sodium hydroxide
• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
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• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2 +  =  +  + 

By formula: 2HNaO + C₂H₃FO = C₂H₃NaO₂ + FNa + H₂O

2 +  =  + 2 + 2

By formula: 2HNaO + C₂H₆O₄ = H₂ + 2CHNaO₂ + 2H₂O

 +  =

By formula: HNaO + C₂H₂O = C₂H₃NaO₂

C₂Na₂ (cr) + 2 (l) = 2( • 1418) (solution) +  (g)

By formula: C₂Na₂ (cr) + 2H₂O (l) = 2(HNaO • 1418H₂O) (solution) + C₂H₂ (g)

C₂HNa (cr) +  (l) = ( • 1418) (solution) +  (g)

By formula: C₂HNa (cr) + H₂O (l) = (HNaO • 1418H₂O) (solution) + C₂H₂ (g)

3 +  = CNa₂O₃ +  +  + 

By formula: 3HNaO + C₃H₅ClO₂ = CNa₂O₃ + C₂H₆O + ClNa + H₂O

2 +  =  +  + CNO.Na

By formula: 2HNaO + CBrN = BrNa + H₂O + CNO.Na

2 +  =  +  + CNO.Na

By formula: 2HNaO + CIN = INa + H₂O + CNO.Na

2 +  =  +  + CNO.Na

By formula: 2HNaO + CClN = ClNa + H₂O + CNO.Na

 +  =  + 

By formula: C₂HBr₃O + HNaO = CHNaO₂ + CHBr₃

 +  =  + 

By formula: HNaO + C₂HCl₃O = CHNaO₂ + CHCl₃

 +  =  + 

By formula: HNaO + C₂H₅NO = C₂H₃NaO₂ + H₃N

C₆H₅NaO (cr) +  (l) =  (cr) +  (cr)

By formula: C₆H₅NaO (cr) + H₂O (l) = C₆H₆O (cr) + HNaO (cr)

C₂H₅NaO (cr) +  (l) =  (cr) +  (l)

By formula: C₂H₅NaO (cr) + H₂O (l) = HNaO (cr) + C₂H₆O (l)

 (cr) +  (l) =  (cr) +  (l)

By formula: CH₃NaO (cr) + H₂O (l) = HNaO (cr) + CH₄O (l)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A., The heat of hydrolysis of acetyl fluoride, J. Chem. Soc., 1950, 1099. [all data]

Carson and Skinner, 1949
Carson, A.S.; Skinner, H.A., 201. Carbon-halogen bond energies in the acetyl halides, J. Chem. Soc., 1949, 936-939. [all data]

Jenkins and Style, 1953
Jenkins, A.D.; Style, D.W.G., The thermochemistry and pyrolysis of bishydroxymethyl, J. Chem. Soc., 1953, 2337-23. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Nuttall, Laufer, et al., 1971
Nuttall, R.L.; Laufer, A.H.; Kilday, M.V., The enthalpy of formation of ketene, J. Chem. Thermodyn., 1971, 3, 167-174. [all data]

Rice and Greenberg, 1934
Rice, F.O.; Greenberg, J., Ketene. III. Heat of formation and heat of reaction with alcohols, J. Am. Chem. Soc., 1934, 38, 2268-2270. [all data]

Johnson, van Deventer, et al., 1973
Johnson, G.K.; van Deventer, E.H.; Ackerman, J.P.; Hubbard, W.N.; Osborne, D.W.; Flotow, H.L., J. Chem. Thermodyn., 1973, 5, 57. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Davies, Finch, et al., 1980
Davies, R.H.; Finch, A.; Gardner, P.J., The standard enthalpy of formation of liquid and gaseous ethylchloroformate (C₃H₅O₂Cl), J. Chem. Thermodyn., 1980, 12, 291-296. [all data]

Lord and Woolf, 1954
Lord, G.; Woolf, A.A., The cyanogen halides. Part III. Their heats of formation and free energies, J. Chem. Soc., 1954, 2546-2551. [all data]

Pritchard and Skinner, 1950, 2
Pritchard, H.O.; Skinner, H.A., The heats of hydrolysis of chloral and bromal, and the C-C bond dissociation energies in chloral and bromal, J. Am. Chem. Soc., 1950, 1928-1931. [all data]

Calvet, 1933
Calvet, E., Mesures thermochimiques directes en chimie organique vitesses et chaleurs de saponification des amides. II.-Mesures effectuees et resultats obtenus, J. Chim. Phys., 1933, 30, 140-146. [all data]

Leal, Pires de Matos, et al., 1991
Leal, J.P.; Pires de Matos, A.; Martinho Simões, J.A., J. Organometal. Chem., 1991, 403, 1. [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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