β-Pinene
- Formula: C10H16
- Molecular weight: 136.2340
- IUPAC Standard InChIKey: WTARULDDTDQWMU-UHFFFAOYSA-N
- CAS Registry Number: 127-91-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-; 2(10)-Pinene; Nopinen; Nopinene; Pseudopinen; Pseudopinene; Terebenthene; 6,6-Dimethyl-2-methylene-bicyclo[3.1.1]heptane; Pinene, β; 2,2,6-Trimethylbicyclo(3.1.1)hept-2-ene; Bicyclo[3.1.1]heptane-6,6-trimethyl, 2-methylene; (.+/-.)-β-Pinene; NSC 21447; beta-Pinene; (-)-β-pinene; (+)-β-pinene; β-Pinene [1R-(+), 1S-(-)]; 1S-(-)-β-pinene; Bicyclo[3.1.1] heptane-6,6-dimethyl-2-methyl; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane (β-pinene); pin-2(10)-ene
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | ZB-1 | ZB-1 | ZB-1 | ZB-1 | ZB-1 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Temperature (C) | 100. | 110. | 120. | 130. | 140. |
I | 981.73 | 985.97 | 990.18 | 995.018 | 1000. |
Reference | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | ZB-1 | ZB-1 | ZB-1 | ZB-1 | ZB-1 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.32 | 0.32 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Temperature (C) | 40. | 50. | 60. | 70. | 80. |
I | 958.28 | 961.96 | 965.76 | 969.63 | 973.6 |
Reference | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 | Hoskovec, Grygarová, et al., 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Packed | Packed |
---|---|---|---|---|---|
Active phase | ZB-1 | DB-1 | SE-30 | OV-101 | OV-101 |
Column length (m) | 30. | 28. | 40. | 2. | 2. |
Carrier gas | He | He | Ar | Ar | |
Substrate | W-AW-DMCS | W-AW-DMCS | |||
Column diameter (mm) | 0.32 | 0.25 | 0.35 | ||
Phase thickness (μm) | 0.25 | 0.25 | 0.35 | ||
Temperature (C) | 90. | 150. | 100. | 130. | 140. |
I | 977.62 | 971. | 980.3 | 993. | 999. |
Reference | Hoskovec, Grygarová, et al., 2005 | Viswanathan, Maridass, et al., 2002 | Tudor, 1997 | Szabolcs, Benecke, et al., 1985 | Szabolcs, Benecke, et al., 1985 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | OV-101 | OV-101 | OV-101 | OV-101 |
Column length (m) | 2. | 2. | |||
Carrier gas | Ar | Ar | |||
Substrate | W-AW-DMCS | W-AW-DMCS | |||
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 150. | 160. | 130. | 140. | 150. |
I | 1004. | 1009. | 993. | 999. | 1004. |
Reference | Szabolcs, Benecke, et al., 1985 | Szabolcs, Benecke, et al., 1985 | Benecke, Thieme, et al., 1982 | Benecke, Thieme, et al., 1982 | Benecke, Thieme, et al., 1982 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | Apiezon L | SE-30 | SE-30 | SE-30 |
Column length (m) | 45. | 80. | 80. | 80. | |
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.5 | 0.5 | 0.5 | |
Phase thickness (μm) | 0.8 | 0.8 | 0.8 | ||
Temperature (C) | 160. | 100. | 100. | 110. | 130. |
I | 1009. | 1002. | 980.8 | 985.1 | 993.1 |
Reference | Benecke, Thieme, et al., 1982 | Morishita, Okano, et al., 1980 | Saeed, Redant, et al., 1979 | Saeed, Redant, et al., 1979 | Saeed, Redant, et al., 1979 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Packed | Capillary |
---|---|---|---|---|---|
Active phase | SF-96 | SF-96 | Apiezon L | Squalane | SF-96 |
Column length (m) | 152. | 15. | 152. | ||
Carrier gas | He | ||||
Substrate | Chromosorb P | ||||
Column diameter (mm) | 0.8 | 0.25 | 0.8 | ||
Phase thickness (μm) | |||||
Temperature (C) | 100. | 100. | 100. | 86. | 100. |
I | 980. | 978.2 | 993. | 966. | 983. |
Reference | Kepner, Ellison, et al., 1974 | Andersen and Syrdal, 1970 | Andersen and Syrdal, 1970 | Hively and Hinton, 1968 | Sakai, Maarse, et al., 1967 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hoskovec, Grygarová, et al., 2005
Hoskovec, Michal; Grygarová, Dana; Cvacka, Josef; Streinz, Ludvík; Zima, Jirí; Verevkin, Sergey P.; Koutek, Bohumír,
Determining the vapour pressures of plant volatiles from gas chromatographic retention data,
Journal of Chromatography A, 2005, 1083, 1-2, 161-172, https://doi.org/10.1016/j.chroma.2005.06.006
. [all data]
Viswanathan, Maridass, et al., 2002
Viswanathan, M.B.; Maridass, M.; Thangadurai, D.; Ramesh, N.,
Chemical constituents of the fruit essential oil of Diospyros malabarica (Desr.) Kostel (Ebenaceae),
Acta Pharmaceutica, 2002, 52, 207-211. [all data]
Tudor, 1997
Tudor, E.,
Temperature dependence of the retention index for perfumery compounds on a SE-30 glass capillary column. I. Linear equations,
J. Chromatogr. A, 1997, 779, 1-2, 287-297, https://doi.org/10.1016/S0021-9673(97)00453-6
. [all data]
Szabolcs, Benecke, et al., 1985
Szabolcs, N.; Benecke, R.; Thieme, H.,
Természetes eredetu növényi anyagok gázkromatográfiás retenciós tulajdonságai. I. A lavandula- és lavandinolaj fo kimponenseinek retenciós indexei,
Acta Pharm. Hung., 1985, 55, 49-58. [all data]
Benecke, Thieme, et al., 1982
Benecke, R.; Thieme, H.; Nyiredy, Sz.,
Retentionsverhalten der Hauptkomponenten der Lavendel und Lavandinöle an Verschiedenen stationären Phasen in Abhängigkeit von der Säulentemperatur,
J. Chromatogr., 1982, 238, 1, 75-87, https://doi.org/10.1016/S0021-9673(00)82713-2
. [all data]
Morishita, Okano, et al., 1980
Morishita, F.; Okano, T.; Kojima, T.,
Retention indices of monocyclic monoterpene hydrocarbons,
Bunseki Kagaku, 1980, 29, 1, 48-53, https://doi.org/10.2116/bunsekikagaku.29.48
. [all data]
Saeed, Redant, et al., 1979
Saeed, T.; Redant, G.; Sandra, P.,
Kovats Indices of Monoterpene Hydrocarbons on Glass Capillary Columns,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1979, 2, 2, 75-76, https://doi.org/10.1002/jhrc.1240020208
. [all data]
Kepner, Ellison, et al., 1974
Kepner, R.E.; Ellison, B.O.; Breckenridge, M.; Connolly, G.; Madden, S.C.; Muller, C.J.,
Volatile terpenes in California Bay foliage. Changes in composition during maturation,
J. Agric. Food Chem., 1974, 22, 5, 781-784, https://doi.org/10.1021/jf60195a027
. [all data]
Andersen and Syrdal, 1970
Andersen, N.H.; Syrdal, D.D.,
Terpenes and sesquiterpenes of chamaecyparis nootkatensis leaf oil,
Phytochemistry, 1970, 9, 6, 1325-1340, https://doi.org/10.1016/S0031-9422(00)85326-1
. [all data]
Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E.,
Variation of the retention index with temperature on squalane substrates,
J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203
. [all data]
Sakai, Maarse, et al., 1967
Sakai, T.; Maarse, H.; Kepner, R.E.; Jennings, W.G.; Longhurst, W.M.,
Volatile components of Douglas fir needles,
J. Agric. Food Chem., 1967, 15, 6, 1070-1072, https://doi.org/10.1021/jf60154a027
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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