Aluminum oxide anion
- Formula: AlO-
- Molecular weight: 42.9815
- CAS Registry Number: 12758-12-2
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 212.75 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1979 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
AlO- + = HAlO
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1539. ± 40. | kJ/mol | D-EA | Desai, Wu, et al., 1996 | gas phase |
ΔrH° | 1505. ± 17. | kJ/mol | G+TS | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1509. ± 41. | kJ/mol | H-TS | Desai, Wu, et al., 1996 | gas phase |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO |
By formula: (AlO- • 4294967295Al) + Al = AlO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 622. ± 27. | kJ/mol | N/A | Desai, Wu, et al., 1996 | gas phase |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
2.600 ± 0.010 | LPES | Desai, Wu, et al., 1996 | |
3.62 ± 0.13 | TDEq | Srivastava, Uy, et al., 1972 | EA: near EA(Cl) |
Protonation reactions
AlO- + = HAlO
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1539. ± 40. | kJ/mol | D-EA | Desai, Wu, et al., 1996 | gas phase |
ΔrH° | 1505. ± 17. | kJ/mol | G+TS | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1509. ± 41. | kJ/mol | H-TS | Desai, Wu, et al., 1996 | gas phase |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Desai, Wu, et al., 1996
Desai, S.R.; Wu, H.; Wang, L.-S.,
Vibrationally Resolved Photoelectron Spectroscopy of AlO- and AlO2-,
Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 75, https://doi.org/10.1016/S0168-1176(96)04443-6
. [all data]
Damrauer, Krempp, et al., 1991
Damrauer, R.; Krempp, M.; Schmidt, M.W.; Gordon, M.S.,
Gas-Phase Chemistry of the Dimethylaluminum Oxide Ion and Related Aluminum Oxide Ions - Comparison of Reactivity with Siloxide Ions,
J. Am. Chem. Soc., 1991, 113, 7, 2393, https://doi.org/10.1021/ja00007a007
. [all data]
Srivastava, Uy, et al., 1972
Srivastava, R.D.; Uy, O.M.; Farber, M.,
Effusion mass spectrometric study of the thermodynamic properties of AlO- and AlO2-,
J. Chem. Soc. Faraday Trans. 2, 1972, 1, 1388. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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