tris(η5-2,4-cyclopentadien-1-yl)thulium
- Formula: C15H15Tm
- Molecular weight: 364.2138
- CAS Registry Number: 1272-26-0
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 61.8 ± 6.2 | kJ/mol | Review | Martinho Simões |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 111.3 ± 3.5 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Devyatykh, Rabinovitch, et al., 1974.; AC |
| ΔsubH° | 111.3 ± 3.5 | kJ/mol | CC-SB | Devyatykh, Borisov, et al., 1973 | MS |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 109.2 ± 2.1 | 338. to 438. | ME | Haug, 1971 | See also Haug, 1971, 2.; AC |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Devyatykh, Rabinovitch, et al., 1974
Devyatykh, C.G.; Rabinovitch, I.B.; Tel'noi, V.I.; Borisov, G.K.; Zyazina, L.F.,
Dokl. Akad. Nauk SSSR, 1974, 217, 673. [all data]
Devyatykh, Borisov, et al., 1973
Devyatykh, G.G.; Borisov, G.K.; Zyuzina, L.F.; Krasnova, S.G.,
Dokl. Akad. Nauk SSSR, 1973, 212, 1, 127. [all data]
Haug, 1971
Haug, H.O.,
Ges. Kernforsch m.b.H. [Rep.] KFK-1283, 1971, 23. [all data]
Haug, 1971, 2
Haug, H.O.,
Dampfdruckmessungen von cyclopentadienylkomplexen des urans und einiger lanthaniden nach der effusionsmethode,
Journal of Organometallic Chemistry, 1971, 30, 1, 53-57, https://doi.org/10.1016/S0022-328X(00)82595-4
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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