Titanocene dichloride

• Formula: C₁₀H₁₀Cl₂Ti
• Molecular weight: 248.959
• IUPAC Standard InChI: InChI=1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2 Copy

  
• IUPAC Standard InChIKey: XKLWATAZDMHTSH-UHFFFAOYSA-L Copy
• CAS Registry Number: 1271-19-8
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Titanium, dichlorobis(η5-2,4-cyclopentadien-1-yl)-; Titanium, dichlorodi-π-cyclopentadienyl-; bis(η5-Cyclopentadienyl)titanium dichloride; Bis(π-cyclopentadienyl)titanium dichloride; Bis(cyclopentadienyl)titanium dichloride; Dichlorobis(π-cyclopentadienyl)titanium; Dichlorobis(cyclopentadienyl)titanium; Dichlorodi-π-cyclopentadienyltitanium; Dichlorodicyclopentadienyltitanium; Dichlorotitanocene; Dicyclopentadienyldichlorotitanium; Dicyclopentadienyltitanium dichloride; Bis(π-cyclopentadienyl)dichlorotitanium; Dichlorobis(η5-cyclopentadienyl)titanium; Dichlorobis(η5-2,4-cyclopentadien-1-yl)titanium; NCI-C04502; Titanium, bis(cyclopentadienyl)dichloride-; Bis(cyclopentadienyl)dichlorotitanium; Dichlorobis(1,3-cyclopentadiene)titanium; NSC 78453; dichlorobis(η-cyclopentadienyl)titanium
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₁₀H₁₀I₂Ti (solution) +  (solution) = 2C₁₀H₁₀ClITi (solution)

By formula: C₁₀H₁₀I₂Ti (solution) + C₁₀H₁₀Cl₂Ti (solution) = 2C₁₀H₁₀ClITi (solution)

C₃₀H₂₈Fe₂Ti (cr) + 2( • 4.40) (solution) = 2 (cr) +  (cr)

By formula: C₃₀H₂₈Fe₂Ti (cr) + 2(HCl • 4.40H₂O) (solution) = 2C₁₀H₁₀Fe (cr) + C₁₀H₁₀Cl₂Ti (cr)

C₂₂H₂₀O₂Ti (cr) + 2( • 5.55) (solution) = 2 (cr) +  (cr)

By formula: C₂₂H₂₀O₂Ti (cr) + 2(HCl • 5.55H₂O) (solution) = 2C₆H₆O (cr) + C₁₀H₁₀Cl₂Ti (cr)

C₁₄H₁₀Cl₆O₄Ti (cr) + 2( • 4.40) (solution) =  (cr) + 2 (cr)

By formula: C₁₄H₁₀Cl₆O₄Ti (cr) + 2(HCl • 4.40H₂O) (solution) = C₁₀H₁₀Cl₂Ti (cr) + 2C₂HCl₃O₂ (cr)

C₁₀H₁₀N₆Ti (cr) + 2( • 4.18) (solution) =  (cr) + 2 (g)

By formula: C₁₀H₁₀N₆Ti (cr) + 2(HCl • 4.18H₂O) (solution) = C₁₀H₁₀Cl₂Ti (cr) + 2HN₃ (g)

C₁₄H₁₀F₆O₄Ti (cr) + 2( • 4.40) (solution) =  (cr) + 2 (l)

By formula: C₁₄H₁₀F₆O₄Ti (cr) + 2(HCl • 4.40H₂O) (solution) = C₁₀H₁₀Cl₂Ti (cr) + 2C₂HF₃O₂ (l)

 (cr) + 2( • 5.55) (solution) =  (cr) + 2 (g)

By formula: C₁₂H₁₆Ti (cr) + 2(HCl • 5.55H₂O) (solution) = C₁₀H₁₀Cl₂Ti (cr) + 2CH₄ (g)

C₁₁H₁₃ClTi (cr) + ( • 4.40) (solution) =  (cr) +  (g)

By formula: C₁₁H₁₃ClTi (cr) + (HCl • 4.40H₂O) (solution) = C₁₀H₁₀Cl₂Ti (cr) + CH₄ (g)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bruce and Tyler, 1985
Bruce, M.R.M.; Tyler, D.R., Organometallics, 1985, 4, 528. [all data]

Dias, Salema, et al., 1982
Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., Organometallics, 1982, 1, 971. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]

Dias, Salema, et al., 1981
Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., J. Organometal. Chem., 1981, 222, 69. [all data]

Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C., Organometallics, 1986, 5, 660. [all data]

Dias, Salema, et al., 1984
Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., Rev. Port. Quím., 1984, 26, 227. [all data]

Calhorda, Gomes da Costa, et al., 1982
Calhorda, M.J.; Gomes da Costa, R.; Dias, A.R.; Martinho Simões, J.A., J. Chem. Soc., Dalton Trans., 1982, 2327.. [all data]

Dias, Dias, et al., 1987
Dias, A.R.; Dias, P.B.; Diogo, H.P.; Galvão, A.M.; Minas da Piedade, M.E.; Martinho Simões, J.A., Organometallics, 1987, 6, 1427. [all data]

Calado, Dias, et al., 1981
Calado, J.C.G.; Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., J. Chem. Soc., Dalton Trans., 1981, 1174.. [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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